Table 3. Experimental details.

Crystal data
Chemical formula	[Ni(NCS)2(C5H12N2S)2]
M r	439.32
Crystal system, space group	Monoclinic, P2/c
Temperature (K)	200
a, b, c (Å)	10.7245 (3), 6.2050 (3), 15.1579 (5)
β (°)	103.140 (3)
V (Å3)	982.28 (6)
Z	2
Radiation type	Mo Kα
μ (mm−1)	1.42
Crystal size (mm)	0.12 × 0.09 × 0.07
Data collection
Diffractometer	Stoe IPDS2
Absorption correction	Numerical (X-RED and X-SHAPE; Stoe & Cie, 2002 ▸)
T min, T max	0.716, 0.874
No. of measured, independent and observed [I > 2σ(I)] reflections	9982, 1945, 1607
R int	0.070
(sin θ/λ)max (Å−1)	0.617
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.038, 0.098, 1.05
No. of reflections	1945
No. of parameters	109
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.39, −0.36

Computer programs: X-AREA (Stoe & Cie, 2002 ▸), SHELXS97 (Sheldrick, 2008 ▸), SHELXL2018/3 (Sheldrick, 2015 ▸), XP (Sheldrick, 2008 ▸), DIAMOND (Brandenburg & Putz, 1999 ▸) and publCIF (Westrip, 2010 ▸).