Table 2:
Mass fractions of class-specific SOA tracers generated in laboratory chamber oxidation experiments as a function of SOA and SOC with propagated analytical uncertainties. DHOPA is a tracer of SOA from monoaromatic VOCs, phthalic acid from diaromatic VOCs, and methyl-nitrocatechols from cresols. Measurement uncertainties for individual species are given in Table S1.
| SOA Tracer | Precursor | Oxidant | fSOA (uncertainty) | fSOC (uncertainty) |
|---|---|---|---|---|
| DHOPA | ||||
| Benzene | NOx | 0.00013 (0.00002) | 0.00029 (0.00004) | |
| Toluene | NOx | 0.0032 (0.0004) | 0.0070 (0.0008) | |
| o-Xylene | NOx | 0.0024 (0.0003) | 0.0047 (0.0006) | |
| m-Xylene | NOx | 0.0036 (0.0004) | 0.0064 (0.0008) | |
| p-Xylene | NOx | 0.0039 (0.0005) | 0.0072 (0.0009) | |
| Ethylbenzene | NOx | 0.00015 (0.00002) | 0.00031 (0.00004) | |
| 1,2,4-Trimethylbenzene | NOx | 0.0022 (0.0003) | 0.0035 (0.0004) | |
| 1,3,5-Trimethylbenzene | NOx | 0.00035 (0.00004) | 0.00052 (0.00006) | |
| Benzene | H2O2 | 0.00013 (0.00002) | 0.00042 (0.00005) | |
| Toluene | H2O2 | 0.0068 (0.0008) | 0.015 (0.002) | |
| Phthalic acid | ||||
| Naphthalene | NOx | 0.024 (0.002) | 0.046 (0.005) | |
| 1-Methylnaphthalene | NOx | 0.0075 (0.0008) | 0.013 (0.001) | |
| Naphthalene | H2O2 | 0.055 (0.005) | 0.108 (0.011) | |
| 1-Methylnaphthalene | H2O2 | 0.0068 (0.0007) | 0.0141 (0.0014) | |
| Methyl-nitrocatechols1 | ||||
| o-Cresol | NOx | 0.041 (0.010) | 0.073 (0.072) | |
| m-Cresol | NOx | 0.279 (0.069) | 0.494 (0.122) | |
| p-Cresol | NOx | 0.057 (0.010) | 0.111 (0.020) | |
The sum of 4-methyl-5-nitrocatechol and 3-methyl-6-nitrocatechol