Table 9.

Ginsenosides analysis of Panax species using HPLC-MS

Method	Species	Part	Analytes	Reference
HPLC-MS	P. ginseng	Root	Ginsenosides Rb1, Rb2, Rc, Rd, Re, Rf, Rg1, Rg2	[118]
HPLC-ESI-MS	P. ginseng	Root	Ginsenosides Rg1, Re, Rb1, Rc, Rb2, Rd	[18]
HPLC-FD-MS	P. ginseng	Ginseng extract	Ginsenosides Rb1, Rb2, Rc, Rd, Re, Rf, Rg1 and Rg2	[134]
HPLC-ESI-MS/MSn	P. ginseng	Root	Ginsenosides Rg1, 20(S)-Rg2, Rb1, Rc, Rh2, malonyl-ginsenoside Rb2 and Rc	[75]
HPLC-ESI-MS/MS	P. ginseng	Root	Low-polar ginsenosides	[80]
UHPLC-MS	P. ginseng	Root	Ginsenosides Rb1, Rb2, Rg1, Rg2, Rg3, Rc, Rd, Re, Rf	[171]
HPLC-MS/MS	P. ginseng	Root	Ginsenosides Rg1, Re, Rf, Rb1, Rc, Rb2, Rd, Rg2, Rh1, F1, F2, Rg3, PPT	[122]
HPLC-MS/MS	P. ginseng	Fresh root	Ginsenosides Rg1, Re, Rf, Rb1, Rb2, Rd, 20(S)-Rg2, Rc, 20(S)-Rh1, F1, F2, 20(S)-Rg3, 20(S)-protopanaxatriol, compound K, 20(S)-Rh2	[172]
HPLC-Qtrap-MS	P. ginseng	Root	Ginsenosides	[173]
HPLC-MS	P. ginseng	Root	Notoginsenoside R1, ginsenoside Rb2, Re, Rb1, Rc, Rg1, Rb3, Rf, F1, Rd, Rh1, Rg2, F2, Rg3, Rh2, compound K	[174]
LC-MS/MS	P. ginseng	Root	15 ginsenosides	[175]
UHPLC-HRMS	P. quinquefolius	Root	Ginsenosides Rb1, Rb2, Rb3, Rc, Rd, Re, Rf, Rg1, Rg2, Rg3, Rh1, Rh2, Ro, F1, F2, F3, pseudoginsenoside F11, notoginsenosides R1, R2	[93]
HPLC-APCI-MS	P. quinquefolius	Root	24(R)-pseudoginsenoside F11	[50]
UPLC-MS/MS	P. quinquefolius	Different parts	22 ginsenosides	[176]
HPLC-MS	P. ginseng, P. quinquefolius	Root	Ginsenosides Rb1, Rb2, Rc, Ro, Rd, Re, Rf, Rg1, pseudoginsenoside F11	[88]
HPLC-MS	P. ginseng, P. quinquefolius	Root	Ginsenoside Rf, 24(R)-pseudoginsenoside F11	[89]
UHPLC-ESI-MS	P. notoginseng	Different parts	Metabolite profiling	[112]
HPLC-MS	P. notoginseng	extraction	Ginsenosides Rg1, Rb1, notoginsenoside R1	[177,178]
UHPLC-MS/MS	P. notoginseng	Extract	Notoginsenoside R1, ginsenosides Rg1, Rb1, Re, Rd	[120]
UPLC-MS/MS	P. notoginseng	Compounds	Notoginsenoside R1, ginsenosides Rg3, Rd, Rg2, Rb2, Rf, Rg1, Rb1, Re	[179]
HPLC-MS	P. notoginseng	Root	Notoginsenoside R1, ginsenosides Rg1, Rb1, Rd, F2, Re	[180]
LC-Q-Trap-MS	P. notoginseng	Extraction	Notoginseng total saponins	[181]
LC-MS/MS	Steamed notoginseng	Rat plasma	23 triterpenoids	[182]
UHPLC-MS	P. japonicus	Leaf	Chikusetsusaponins V, Ib, IV, IVa, IV ethyl ester	[183]
HPLC-MS	P. ginseng, P. quinquefolius, P. notoginseng	Root	Ginsenosides Ro, Ra2, Ra3, Rb1, Rb2, Rb3, Rc, Rd, Re, Rg1, Rg2, 20(S)-Rg3, Rf, notoginsenosides R1, R2, R4 and 24(R)-pseudoginsenoside F11	[91]
HPLC-APCI-MS	P. quinquefolius, P. ginseng, P. notoginseng	Root	Ginsenosides Rf, F11, notoginsenoside R1	[51]