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. 2020 Dec 23;26(1):45. doi: 10.3390/molecules26010045

Table 2.

Enantioselective analysis of some chiral constituents of C. taxifolium EO on diethyl-tert-butyldimethylsilyl-β-cyclodextrin column.

Component RT a (min.) LRI b Enantiomer Percentage ee%
(1S,5R)-(+)-α-thujene c 12.96 920 16.1 67.8
(1R,5S)-(−)-α-thujene c 13.20 924 83.9
(1R,5R)-(+)-α-pinene 13.72 933 92.8 85.5
(1S,5S)-(−)-α-pinene 13.85 935 7.2
(1R,5R)-(+)-β-pinene 15.28 959 5.0 90.0
(1S,5S)-(−)-β-pinene 15.76 967 94.9
(1R,5R)-(+)-sabinene 16.85 985 43.9 12.3
(1S,5S)-(−)-sabinene 17.66 998 56.2
(S)-(−)-limonene 21.55 1061 94.1 88.1
(R)-(+)-limonene 22.59 1078 5.9
(R)-(−)-linalool 29.84 1198 33.7 32.7
(S)-(+)-linalool 30.47 1209 66.3
(S)-(+)-terpinen-4-ol 33.98 1270 45.4 9.3
(R)-(−)-terpinen-4-ol 34.12 1272 54.6
(S)-(−)-α-terpineol 36.37 1312 85.6 71.2
(R)-(+)-α-terpineol 37.13 1326 14.4
(R)-(+)-germacrene D 38.74 1354 5.5 89.0
(S)-(−)-germacrene D 45.15 1474 94.5

a Retention time (RT); b Linear Retention Index (LRI) calculated on the 30% diethyl-tert-butyldimethylsilyl-β-cyclodextrin in PS-086 column; c tentative enantiomer identification according to [38]; ee = enantiomeric excess.