Table 2.
Component | RT a (min.) | LRI b | Enantiomer Percentage | ee% |
---|---|---|---|---|
(1S,5R)-(+)-α-thujene c | 12.96 | 920 | 16.1 | 67.8 |
(1R,5S)-(−)-α-thujene c | 13.20 | 924 | 83.9 | |
(1R,5R)-(+)-α-pinene | 13.72 | 933 | 92.8 | 85.5 |
(1S,5S)-(−)-α-pinene | 13.85 | 935 | 7.2 | |
(1R,5R)-(+)-β-pinene | 15.28 | 959 | 5.0 | 90.0 |
(1S,5S)-(−)-β-pinene | 15.76 | 967 | 94.9 | |
(1R,5R)-(+)-sabinene | 16.85 | 985 | 43.9 | 12.3 |
(1S,5S)-(−)-sabinene | 17.66 | 998 | 56.2 | |
(S)-(−)-limonene | 21.55 | 1061 | 94.1 | 88.1 |
(R)-(+)-limonene | 22.59 | 1078 | 5.9 | |
(R)-(−)-linalool | 29.84 | 1198 | 33.7 | 32.7 |
(S)-(+)-linalool | 30.47 | 1209 | 66.3 | |
(S)-(+)-terpinen-4-ol | 33.98 | 1270 | 45.4 | 9.3 |
(R)-(−)-terpinen-4-ol | 34.12 | 1272 | 54.6 | |
(S)-(−)-α-terpineol | 36.37 | 1312 | 85.6 | 71.2 |
(R)-(+)-α-terpineol | 37.13 | 1326 | 14.4 | |
(R)-(+)-germacrene D | 38.74 | 1354 | 5.5 | 89.0 |
(S)-(−)-germacrene D | 45.15 | 1474 | 94.5 |
a Retention time (RT); b Linear Retention Index (LRI) calculated on the 30% diethyl-tert-butyldimethylsilyl-β-cyclodextrin in PS-086 column; c tentative enantiomer identification according to [38]; ee = enantiomeric excess.