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. 2021 Jan 12;11:788. doi: 10.1038/s41598-020-80876-z

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© The Author(s) 2021

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Femtosecond time-resolved (pump-probe) laser spectroscopic observations of the dissociative electron transfer (DET) reaction between cisplatin (CDDP) and Rhodamine-B (BV10) in aqueous solutions. (A) Transient absorption measurements of BV10 cation radical (RDM-B^+•) in 10 μM BV10 only, 3 mM CDDP only, and the mixtures of 10 μM BV10 and 1.5 mM or 3 mM CDDP. (B,C) Transient absorption measurements of prehydrated electrons (e_pre⁻) in pure water, 60 μM and 120 μM BV10 only solutions, and in pure water, 3 mM CDDP only and the mixtures of 3 mM CDDP with 60 μM or 120 μM BV10.