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. 2021 Jan 12;11:598. doi: 10.1038/s41598-020-79893-9

Table 1.

Competitive stability of complexes 1 and 11.

pH Complex Gradienta r2 b % Gd3+ retentionc
5.0 GdCl3 3.83 × 10−2 0.998 0
5.0 1 1.67 × 10−2 0.971 56.5 ± 3.4
5.0 11 3.34 × 10−2 0.995 12.8 ± 0.4
5.8 GdCl3 3.57 × 10−2 0.993 0
5.8 1 1.82 × 10−2 0.978 49.0 ± 2.8
5.8 11 2.94 × 10−2 0.998 17.6 ± 0.6

aSlope of the line of best fit resulting from a plot of the average data using 10 different concentrations (2.0–250 μM).

bRegression analysis of the line of best fit.

cPercentage of Gd3+ retained by the phosphonium complex over a period of 24 h, as determined by the shift in absorbance from 433 to 573 nm, averaged across all data points.