Table 1.
pH | Complex | Gradienta | r2 b | % Gd3+ retentionc |
---|---|---|---|---|
5.0 | GdCl3 | 3.83 × 10−2 | 0.998 | 0 |
5.0 | 1 | 1.67 × 10−2 | 0.971 | 56.5 ± 3.4 |
5.0 | 11 | 3.34 × 10−2 | 0.995 | 12.8 ± 0.4 |
5.8 | GdCl3 | 3.57 × 10−2 | 0.993 | 0 |
5.8 | 1 | 1.82 × 10−2 | 0.978 | 49.0 ± 2.8 |
5.8 | 11 | 2.94 × 10−2 | 0.998 | 17.6 ± 0.6 |
aSlope of the line of best fit resulting from a plot of the average data using 10 different concentrations (2.0–250 μM).
bRegression analysis of the line of best fit.
cPercentage of Gd3+ retained by the phosphonium complex over a period of 24 h, as determined by the shift in absorbance from 433 to 573 nm, averaged across all data points.