Table 1. Scrubbing Studies for Removal of Co-Extracted Nd(III)a.
| Phase ratio (MP:LP) | [HCl]scrub, mol L–1 | [Dy(III)]scrub, g L–1 | %Scrubbing, Nd(III) | %Stripping, Dy(III) |
|---|---|---|---|---|
| 1:1 | 0.5 | 0.0 | 99.3 | 65.1 |
| 1.0 | 0.0 | 100 | 46.6 | |
| 2.0 | 0.0 | 96.4 | 24.4 | |
| 1.0 | 0.9 | 99.0 | b | |
| 2.0 | 1.9 | 99.5 | b | |
| 1:2 | 1.0 | 0.0 | 77.3 | 23.5 |
| 1.0 | 0.9 | 81.0 | 14.8 | |
| 1.0 | 1.9 | 79.7 | b | |
| 2.0 | 0.9 | 81.1 | b | |
| 2.0 | 1.9 | 81.5 | b |
The variables within the PEG 200 scrub solution were: HCl concentration, Dy(III) concentration, and MP:LP phase ratio. The loaded LP phase contained [Nd] = 0.7 g L–1 and [Dy] = 0.9 g L–1. Temperature: 21 ± 1 °C.
Mass balance calculations based on scrub raffinate concentrations indicated that there was net extraction of Dy(III) from the scrub feed, hence no stripping percentage can be mentioned.