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. 2020 Dec 15;6(1):416–424. doi: 10.1021/acsomega.0c04826

Table 3. Energy Transfer Rate Prefactor and the Norm of the Effective Dipole Moment of the Ligand Field for Each Eu(III) Complex.

  energy transfer rate prefactora [(eV)−2 s–1]
μb (Debye)
Eu(III) complex 5D0 5D1 5D2 T1, 7F S0, 5D0
1 4.6e+16 2.4e+16 1.9e+17 0.63 0.76
1 + 2 eq. of TPPO 4.8e+17 3.8e+16 1.3e+17 1.30 1.18
1 + 1 eq. of TPPO and TBPO 1.2e+17 2.8e+16 2.3e+17 1.90 1.67
2 8.4e+17 4.4e+16 1.4e+17 2.36 2.76
a

Details of the calculation of the energy transfer rate prefactor are given in S3.

b

Details of the norm of the effective dipole moment of the ligand field are given in S4.