Table 2.
Reaction | Rate constant (molecule−1 cm3 s−1) | Flux (molecule cm−3 s−1) | |
---|---|---|---|
Befor lockdown (high NOx level) | After lockdown (low NOx level) | ||
NO2 + hv ≥ NO + O(3P) | 5.0 × 10−3 | 3.28 × 109 | 6.05 × 108 |
O(3p) + O2 ≥ O3 | 1.5 × 10−14 | 4.04 × 1012 | 4.04 × 1012 |
NO + O3 ≥ NO2 + O2 | 2.0 × 10−14 | 1.51 × 1023 | 6.28 × 1022 |
NO2 + O3 ≥ NO3 + O2 | 3.2 × 10−17 | 8.05 × 10−6 | 4.03 × 10−6 |
Net flux | - | 1.51 × 1023 | 6.28 × 1022 |