Table 2.
Volatile compounds | RT (min) | KI | Fresh fish | 75 MPa/25 °C | AP/5 °C | AP/25 °C | ||||
---|---|---|---|---|---|---|---|---|---|---|
0 days | 6 days | 15 days | 30 days | 5 days | 15 days | 30 days | 5 days | |||
Alcohols | ||||||||||
Pent-1-en-3-ol | 2.921 | 670 | 0.073 ± 0.006 | 0.081 ± 0.009 | 0.086 ± 0.047 | 0.031 ± 0.006 | 0.074 ± 0.027 | 0.060 ± 0.016 | 0.068 ± 0.005 | nd |
3-Methylbutan-1-ol | 3.847 | 717 | nd | nd | nd | nd | 0.038 ± 0.011d | 0.969 ± 0.066a | 0.497 ± 0.022b | 0.157 ± 0.074c |
2-Methylbutan-1-ol | 3.954 | 720 | nd | nd | nd | nd | 0.009 ± 0.006c | 0.202 ± 0.030a | 0.255 ± 0.058a | 0.084 ± 0.027b |
Butane-2,3-diol | 5.913 | 779 | nd | nd | nd | nd | 0.065 ± 0.032b | 0.145 ± 0.009a | 0.090 ± 0.037ab | 0.108 ± 0.044ab |
Oct-1-en-3-ol | 12.930 | 973 | 0.064 ± 0.063 | 0.078 ± 0.016 | 0.076 ± 0.038 | 0.039 ± 0.003 | 0.052 ± 0.019 | 0.057 ± 0.021 | 0.055 ± 0.004 | nd |
Phenylethyl alcohol | 19.375 | 1108 | nd | nd | nd | nd | 0.014 ± 0.003c | 0.228 ± 0.008a | 0.136 ± 0.035b | 0.222 ± 0.028a |
Aldehydes | ||||||||||
3-Methylbutanal | 2.569 | 642 | nd | nd | nd | 0.022 ± 0.007b | 0.021 ± 0.007b | 0.095 ± 0.042a | 0.072 ± 0.018a | nd |
Hexanal | 5.533 | 768 | 0.362 ± 0.123a | 0.234 ± 0.043abc | 0.164 ± 0.081bc | 0.100 ± 0.034c | 0.340 ± 0.075ab | 0.248 ± 0.024abc | 0.404 ± 0.062a | 0.113 ± 0.002c |
Hept-4-enal | 9.305 | 893 | 0.059 ± 0.010a | 0.046 ± 0.011ab | 0.026 ± 0.007bc | 0.012 ± 0.005c | 0.044 ± 0.003ab | 0.038 ± 0.004b | 0.042 ± 0.010ab | nd |
Heptanal | 9.428 | 898 | 0.067 ± 0.035a | 0.025 ± 0.008ab | 0.034 ± 0.025ab | 0.011 ± 0.006b | 0.037 ± 0.008ab | 0.051 ± 0.012ab | 0.049 ± 0.013ab | nd |
Benzaldehyde | 11.778 | 951 | 0.060 ± 0.036b | 0.052 ± 0.019b | 0.060 ± 0.026ab | 0.045 ± 0.002b | 0.042 ± 0.026b | 0.104 ± 0.034ab | 0.133 ± 0.018a | 0.076 ± 0.029ab |
Octanal | 14.104 | 1004 | 0.023 ± 0.006b | 0.070 ± 0.019a | 0.059 ± 0.025ab | 0.023 ± 0.008b | 0.046 ± 0.016ab | 0.046 ± 0.017ab | 0.078 ± 0.011a | nd |
Hepta-2,4-dienal | 14.420 | 1005 | 0.087 ± 0.021 | 0.062 ± 0.034 | 0.100 ± 0.072 | nd | 0.105 ± 0.012 | 0.098 ± 0.027 | 0.060 ± 0.022 | nd |
Phenylacetaldehyde | 15.747 | 1032 | nd | nd | nd | nd | 0.024 ± 0.014c | 1.363 ± 0.306a | 0.483 ± 0.073b | 0.310 ± 0.161bc |
Nonanal | 19.044 | 1101 | 0.029 ± 0.009 | 0.062 ± 0.014 | 0.087 ± 0.057 | 0.056 ± 0.014 | 0.064 ± 0.019 | 0.078 ± 0.025 | 0.065 ± 0.016 | 0.087 ± 0.012 |
Decanal | 23.852 | 1200 | 0.019 ± 0.020 | 0.022 ± 0.008 | 0.022 ± 0.018 | 0.012 ± 0.007 | 0.019 ± 0.008 | 0.022 ± 0.007 | 0.011 ± 0.002 | 0.024 ± 0.012 |
Alkanes | ||||||||||
Decane | 13.961 | 1000 | 0.096 ± 0.026b | 0.276 ± 0.090a | 0.103 ± 0.047b | 0.087 ± 0.038b | 0.205 ± 0.030ab | 0.157 ± 0.054ab | 0.104 ± 0.017b | nd |
Undecane | 18.644 | 1093 | 0.120 ± 0.025 | 0.450 ± 0.156 | 0.246 ± 0.159 | 0.207 ± 0.060 | 0.291 ± 0.062 | 0.204 ± 0.059 | 0.136 ± 0.014 | 0.356 ± 0.245 |
Dodecane | 23.313 | 1190 | 0.076 ± 0.013 | 0.293 ± 0.116 | 0.196 ± 0.116 | 0.199 ± 0.043 | 0.159 ± 0.038 | 0.111 ± 0.020 | 0.075 ± 0.009 | 0.239 ± 0.156 |
Tridecane | 27.240 | 1290 | 0.039 ± 0.008 | 0.133 ± 0.057 | 0.088 ± 0.053 | 0.099 ± 0.020 | 0.066 ± 0.017 | 0.041 ± 0.001 | 0.028 ± 0.001 | 0.113 ± 0.076 |
Pentadecane | 33.403 | 1496 | 0.097 ± 0.034c | 0.060 ± 0.025c | 0.069 ± 0.032c | 0.055 ± 0.025c | 0.101 ± 0.047c | 0.134 ± 0.055bc | 0.421 ± 0.079a | 0.249 ± 0.114b |
Heptadecane | 37.830 | 1680 | 0.107 ± 0.065bcd | 0.059 ± 0.033d | 0.075 ± 0.056 cd | 0.051 ± 0.028d | 0.083 ± 0.044bcd | 0.080 ± 0.012bc | 0.088 ± 0.015b | 0.148 ± 0.025a |
2,6,10,14-Tetramethylpentadecane | 38.335 | 1700 | 0.164 ± 0.037b | 0.093 ± 0.003b | 0.111 ± 0.050b | 0.085 ± 0.006b | 0.135 ± 0.043b | 0.180 ± 0.032b | 0.080 ± 0.009b | 0.352 ± 0.062a |
Esters | ||||||||||
Ethyl acetate | 2.256 | 616 | 0.025 ± 0.001bc | nd | nd | nd | 0.127 ± 0.016bc | 0.324 ± 0.113ab | 0.325 ± 0.113ab | 0.554 ± 0.279a |
Ethyl 2-methylpropanoate | 4.458 | 735 | nd | nd | nd | nd | nd | nd | nd | 0.560 ± 0.126 |
Ethyl 2-methylbutanoate | 7.356 | 826 | nd | nd | nd | nd | nd | nd | nd | 0.866 ± 0.302 |
Ethyl 4-methylpentanoate | 12.412 | 962 | nd | nd | nd | nd | nd | nd | nd | 2.815 ± 0.591 |
Ketones | ||||||||||
Butan-2-one | 2.141 | 607 | nd | nd | nd | nd | 0.021 ± 0.006b | 0.019 ± 0.009b | 0.021 ± 0.008b | 1.312 ± 0.663a |
Sulphur compounds | ||||||||||
Dimethyl disulphide | 4.098 | 724 | nd | nd | nd | nd | nd | nd | nd | 0.164 ± 0.023 |
Different letters along each row denote significant differences (p < 0.05); absence of letters indicates not statistically significant differences. Values correspond to the peak area of each compound/peak area of internal standard ratio.
KI experiment value of Kovats Index (KI).