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. 2021 Jan 18;11:1668. doi: 10.1038/s41598-021-81047-4

Table 2.

Volatile compounds Atlantic salmon stored at 75 MPa/25 °C and AP/5 °C during 30 days, and at AP/25 °C during 5 days.

Volatile compounds RT (min) KI Fresh fish 75 MPa/25 °C AP/5 °C AP/25 °C
0 days 6 days 15 days 30 days 5 days 15 days 30 days 5 days
Alcohols
Pent-1-en-3-ol 2.921 670 0.073 ± 0.006 0.081 ± 0.009 0.086 ± 0.047 0.031 ± 0.006 0.074 ± 0.027 0.060 ± 0.016 0.068 ± 0.005 nd
3-Methylbutan-1-ol 3.847 717 nd nd nd nd 0.038 ± 0.011d 0.969 ± 0.066a 0.497 ± 0.022b 0.157 ± 0.074c
2-Methylbutan-1-ol 3.954 720 nd nd nd nd 0.009 ± 0.006c 0.202 ± 0.030a 0.255 ± 0.058a 0.084 ± 0.027b
Butane-2,3-diol 5.913 779 nd nd nd nd 0.065 ± 0.032b 0.145 ± 0.009a 0.090 ± 0.037ab 0.108 ± 0.044ab
Oct-1-en-3-ol 12.930 973 0.064 ± 0.063 0.078 ± 0.016 0.076 ± 0.038 0.039 ± 0.003 0.052 ± 0.019 0.057 ± 0.021 0.055 ± 0.004 nd
Phenylethyl alcohol 19.375 1108 nd nd nd nd 0.014 ± 0.003c 0.228 ± 0.008a 0.136 ± 0.035b 0.222 ± 0.028a
Aldehydes
3-Methylbutanal 2.569 642 nd nd nd 0.022 ± 0.007b 0.021 ± 0.007b 0.095 ± 0.042a 0.072 ± 0.018a nd
Hexanal 5.533 768 0.362 ± 0.123a 0.234 ± 0.043abc 0.164 ± 0.081bc 0.100 ± 0.034c 0.340 ± 0.075ab 0.248 ± 0.024abc 0.404 ± 0.062a 0.113 ± 0.002c
Hept-4-enal 9.305 893 0.059 ± 0.010a 0.046 ± 0.011ab 0.026 ± 0.007bc 0.012 ± 0.005c 0.044 ± 0.003ab 0.038 ± 0.004b 0.042 ± 0.010ab nd
Heptanal 9.428 898 0.067 ± 0.035a 0.025 ± 0.008ab 0.034 ± 0.025ab 0.011 ± 0.006b 0.037 ± 0.008ab 0.051 ± 0.012ab 0.049 ± 0.013ab nd
Benzaldehyde 11.778 951 0.060 ± 0.036b 0.052 ± 0.019b 0.060 ± 0.026ab 0.045 ± 0.002b 0.042 ± 0.026b 0.104 ± 0.034ab 0.133 ± 0.018a 0.076 ± 0.029ab
Octanal 14.104 1004 0.023 ± 0.006b 0.070 ± 0.019a 0.059 ± 0.025ab 0.023 ± 0.008b 0.046 ± 0.016ab 0.046 ± 0.017ab 0.078 ± 0.011a nd
Hepta-2,4-dienal 14.420 1005 0.087 ± 0.021 0.062 ± 0.034 0.100 ± 0.072 nd 0.105 ± 0.012 0.098 ± 0.027 0.060 ± 0.022 nd
Phenylacetaldehyde 15.747 1032 nd nd nd nd 0.024 ± 0.014c 1.363 ± 0.306a 0.483 ± 0.073b 0.310 ± 0.161bc
Nonanal 19.044 1101 0.029 ± 0.009 0.062 ± 0.014 0.087 ± 0.057 0.056 ± 0.014 0.064 ± 0.019 0.078 ± 0.025 0.065 ± 0.016 0.087 ± 0.012
Decanal 23.852 1200 0.019 ± 0.020 0.022 ± 0.008 0.022 ± 0.018 0.012 ± 0.007 0.019 ± 0.008 0.022 ± 0.007 0.011 ± 0.002 0.024 ± 0.012
Alkanes
Decane 13.961 1000 0.096 ± 0.026b 0.276 ± 0.090a 0.103 ± 0.047b 0.087 ± 0.038b 0.205 ± 0.030ab 0.157 ± 0.054ab 0.104 ± 0.017b nd
Undecane 18.644 1093 0.120 ± 0.025 0.450 ± 0.156 0.246 ± 0.159 0.207 ± 0.060 0.291 ± 0.062 0.204 ± 0.059 0.136 ± 0.014 0.356 ± 0.245
Dodecane 23.313 1190 0.076 ± 0.013 0.293 ± 0.116 0.196 ± 0.116 0.199 ± 0.043 0.159 ± 0.038 0.111 ± 0.020 0.075 ± 0.009 0.239 ± 0.156
Tridecane 27.240 1290 0.039 ± 0.008 0.133 ± 0.057 0.088 ± 0.053 0.099 ± 0.020 0.066 ± 0.017 0.041 ± 0.001 0.028 ± 0.001 0.113 ± 0.076
Pentadecane 33.403 1496 0.097 ± 0.034c 0.060 ± 0.025c 0.069 ± 0.032c 0.055 ± 0.025c 0.101 ± 0.047c 0.134 ± 0.055bc 0.421 ± 0.079a 0.249 ± 0.114b
Heptadecane 37.830 1680 0.107 ± 0.065bcd 0.059 ± 0.033d 0.075 ± 0.056 cd 0.051 ± 0.028d 0.083 ± 0.044bcd 0.080 ± 0.012bc 0.088 ± 0.015b 0.148 ± 0.025a
2,6,10,14-Tetramethylpentadecane 38.335 1700 0.164 ± 0.037b 0.093 ± 0.003b 0.111 ± 0.050b 0.085 ± 0.006b 0.135 ± 0.043b 0.180 ± 0.032b 0.080 ± 0.009b 0.352 ± 0.062a
Esters
Ethyl acetate 2.256 616 0.025 ± 0.001bc nd nd nd 0.127 ± 0.016bc 0.324 ± 0.113ab 0.325 ± 0.113ab 0.554 ± 0.279a
Ethyl 2-methylpropanoate 4.458 735 nd nd nd nd nd nd nd 0.560 ± 0.126
Ethyl 2-methylbutanoate 7.356 826 nd nd nd nd nd nd nd 0.866 ± 0.302
Ethyl 4-methylpentanoate 12.412 962 nd nd nd nd nd nd nd 2.815 ± 0.591
Ketones
Butan-2-one 2.141 607 nd nd nd nd 0.021 ± 0.006b 0.019 ± 0.009b 0.021 ± 0.008b 1.312 ± 0.663a
Sulphur compounds
Dimethyl disulphide 4.098 724 nd nd nd nd nd nd nd 0.164 ± 0.023

Different letters along each row denote significant differences (p < 0.05); absence of letters indicates not statistically significant differences. Values correspond to the peak area of each compound/peak area of internal standard ratio.

KI experiment value of Kovats Index (KI).