Stereolithography (SLA) |
Resins with photo-active monomers acrylates – epoxides (Ligon et al., 2017) - DC 100 (high accuracy) - DC 500 - DL 350/360 (high flexibility) - AB 001 - GM 08 (high flexibility) - DM 210 - DM 220 |
10 μm (Ngo et al., 2018) |
Fine spatial resolution - high quality (Ngo et al., 2018) - good surface quality - good precision (Ligon et al., 2017) |
Supports limited materials - slow printing - expensive (Ngo et al., 2018) - poor biocompatibility - limited mechanical properties (Ligon et al., 2017) |
Digital light processing (DLP) (Ligon et al., 2017) |
Acrylates - epoxides - plas range (High resolution and chemically resistant) - superCAST - superWAX |
25–100 μm |
High printing accuracy - low cost - shorter build time than SLA - less affected by oxygen inhibition compared to SLA - better surface quality - low initial vat volume is needed |
Limited mechanical properties |
Continuous liquid interphase printing (CLIP) (Ligon et al., 2017) |
Acrylates - rigid polyurethane (RPU) - flexible polyurethane (EPU) (impact resistant) - elastomeric polyurethane - cyanate ester (CE) - prototyping (PR) - |
75 μm |
Higher build speed than DLP |
Low viscosity resin is needed |
Two/multi-photon polymerization (TPP/MPP) (Ligon et al., 2017) |
Acrylates |
100 nm - 5 μm |
High spatial resolution |
Low build speed - limited material |
Powder-bed based methods (selective laser sintering (SLS) -selective laser melting (SLM)) |
Compact fine powder metals - alloys and limited polymers (Ngo et al., 2018) - PA12 – PEEK (Ligon et al., 2017) titanium (biocompatible) - stainless steel - aluminum - cobalt/chrome – nickel-based alloys |
50–250 μm (Ligon et al., 2017) |
Fine resolution - high quality - durable - large surface area, good for scaffolds of tissue engineering - good mechanical properties (SLM) - less anisotropy (Ligon et al., 2017) |
Slow printing - expensive - porosity - lower mechanical properties due to the porous structure (SLS) - high power supply - high printing temp - rough surface - poor reusability of unsintered powder (Ligon et al., 2017) |
Fused deposition modeling (FDM) |
Continuous filament of thermoplastic polymers - continuous fiber-reinforced polymers (Ngo et al., 2018) – PLA (Ligon et al., 2017) - ABS - ASA - Nylon 12 - PC - PPSF/PPSU - PEI or ULTEM (Biocompatible) - PLA – TPU |
50–200 μm (Ngo et al., 2018) |
Low cost - high speed – simplicity (Ngo et al., 2018) |
Weak mechanical properties - limited material (thermoplastics) – layer-by-layer finish (Ngo et al., 2018) - rough surface - high temperature during the extrusion process (incompatible for cells) (Ligon et al., 2017) |
3D dispensing (Ligon et al., 2017) |
Thermoplastics - photoresins - composites - hydrogels - biomaterials |
100 μm - 1cm |
Wide range of materials |
Rough surface - narrow viscosity process window |
3D printing (Binder jetting) (Ligon et al., 2017) |
Stretch - PLA - ceramics |
100 μm |
Fast - allow multi-material AM |
Rough surface - limited strength of parts |
Inkjet printing (Ngo et al., 2018) |
A concentrated dispersion of particles in a liquid (Ink or paste) |
5–200 μm |
Quick printing |
Weak adhesion between layers |
PolyJet (Ligon et al., 2017) |
Acrylates - VeroWhitePlus - digital ABS - FullCure RGD 720 - Rigur RGD 450 - biocompatible material |
25 μm |
Fast - allow multimaterial AM |
Low viscosity ink is needed |
Direct energy deposition (DED) (Ngo et al., 2018) |
Metals and alloys in the form of powder or wire ceramics and polymers |
250 μm |
Reduced manufacturing time and cost - good mechanical properties - accurate composition control - good for repair and retrofitting |
Low accuracy - low surface quality - dense support structure is needed - limitation in printing complex shapes |