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. 2020 Nov 9;26(71):17156–17164. doi: 10.1002/chem.202003271

Figure 1.

Figure 1

Solid state molecular structure of [(C^C^D)AuIII] complexes 35 (left), 39 (middle) and 40 (right). Thermal ellipsoids are set at 30 % probability. Hydrogen atoms are omitted for clarity. Only one molecule of the asymmetric unit of 35 is shown. The asymmetric unit of 35 contains half a molecule hexane (not shown). Selected bond lengths (pm) and angles (°), 35: Au‐C18 211.2 (10), Au‐C1 209.4(10), Au‐C12 200.7(10), Au‐N 212.4(9), C1‐Au‐C12 78.9(4), C12‐Au‐N 80.1(4), C1‐Au‐C18‐F 62.6(9); 39: Au‐C17 204.5(8), Au‐C1 206.4(7), Au‐C12 197.9(8), Au‐C13 207.4(8), C1‐Au‐C12 79.6(4), C12‐Au‐C13 78.2(3); 40: Au‐C17 206.2(14), Au‐C1 206.6(12), Au‐C12 200.3(12), Au‐C13 209.1(12), C1‐Au‐C12 78.9(6), C12‐Au‐C13 78.7(4), C1‐Au‐C17‐C 97.9(1).