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. 2020 Dec 30;11(1):12. doi: 10.3390/bios11010012

Table 2.

Chromatography-coupled detection: selectivity via chromatographic separation of sample components.

DTF
Investigated
Electrode Surface
(Catalyst/Modifier)
Sample Applied Potential L.O.D. Ref.
Thiram CPE Spiked river water +1.1V vs. Ag/AgCl 2.07 µM, [12]
Thiram
Disulfiram
Composite PTFE-graphite paste electrodes Spiked apple samples +1V vs. Ag/AgCl Thiram:
1.66 µM
Disulfiram:
3.37 μM
[60]
Carbathion
Thiram
Zineb
GCE Spiked fruit pulp samples +1.1 V vs. Pd 0.7 μM
Thiram:
1.5 μM
Carbathion:
0.7 μM
[59]
Carbathion
Mancozeb
Propineb
Ziram
not reported +0.6V vs. Pd. Carbathion:
31 nM
Mancozeb:
7 nM
Propineb:
26 nM
Ziram:
26 nM
[10]
Thiram GCE Spiked tap water and beetroot juice +1.4V vs. Ag/AgCl. 13.4 nM [13]
Thiram, disulfiram AuNP-SPCE Spiked apple, grape and lettuce samples +1.2 V vs. Ag/AgCl Thiram:
91 nM
Disulfiram:
0.56 µM
[14]

CPE: carbon paste electrode. GCE: glassy carbon electrode. AuNP-SPCE: Gold nanoparticle modified screen-printed carbon. PTFE: poly(tetrafluoroethylene).