Table 2.
Chemical compositions of different parts (roots, seeds, leaves, and capitula) of the two varieties Anacyclus pyrethrum var. pyrethrum (L.) and Anacyclus pyrethrum var. depressus (Ball).
| N° | RT | m/z Quasi-Molecular Peak | Structural Formula | Compounds | % Area | |||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| A. P var. pyrethrum | A. P var. depressus | |||||||||||
| Roots (Rm) | Seeds (Gm) | Leaves (Fm) | Capitula (Cm) | Roots (Rf) | Seeds (Gf) | Leaves (Ff) | Capitula (Cf) | |||||
| 1 | 4.35 | 231(M + H)+ | C15H19NO | (2,4)-N-isobutyl-2,4-undecadiene-8,10-diynamide | 0.97 | 0.76 | 2.29 | - | 4.84 | 2.20 | 7.07 | - |
| 2 | 4.92 | 246(M)+ | C16H25ON | N-isobutyl-dodeca-2,4,8,10-tetraenamide | 6.79 | 4.44 | 9.45 | 15.91 | 14.14 | 11.41 | 9.15 | 0.57 |
| 3 | 6.12 | 241(M)+ | C9H14F3NO3 | Sarcosine, N-(trifluoroacetyl)-, butyl ester | 2.65 | 0.65 | 4.26 | - | 6.08 | 4.88 | 11.99 | - |
| 4 | 6.44 | 153(M)+ | C4H3N5S | Thiadiazolo[5,4-d]pyrimidin-7-amine | - | - | - | - | 0.74 | - | - | - |
| 5 | 6.98 | 193(M + H)+ | C12H17ON | N-isobutyl-2,4-octadiene-6-monoynamide | 0.76 | 0.68 | 0.68 | 0.74 | 0.69 | 2.04 | 0.82 | - |
| 6 | 7.71 | 116(M)+ | C5H8O3 | Levulinic acid | 37.47 | 50.45 | 7.01 | 3.66 | 15.90 | 14.84 | 17.74 | 30.01 |
| 7 | 8.43 | 104(M)+ | C3H4O4 | Malonic Acid | 8.48 | 6.39 | 16.86 | 6.50 | 6.98 | 11.50 | 8.42 | - |
| 8 | 8.77 | 177(M)+ | C11H15ON | N-isobutyl-2,4-heptadiene-6-monoynamide | - | 1.52 | 6.29 | - | - | - | - | - |
| 9 | 9.38 | 256(M) | C16H32O2 | Palmitic Acid | 2.85 | 2.75 | 3.17 | 8.34 | 5.30 | 7.29 | 3.44 | 0.77 |
| 10 | 9.65 | 285(M)+ | C17H19NO3 | Morphinan-6-One, 4,5α-Epoxy-3-Hydroxy-17-Methyl | 2.17 | 1.31 | 2.86 | 4.93 | 2.21 | 2.00 | 1.65 | - |
| 11 | 10.62 | 147(M + H)+ | C9H8O2 | Cinnamic acid | - | - | 10.53 | - | - | - | - | - |
| 12 | 10.75 | 278(M + H)+ | C18H31NO | 2,4)-undecadiene-8,10-diyne-N-tyramide | 11.09 | 5.34 | 16.50 | 46.07 | 23.61 | 13.32 | 14.15 | 1.58 |
| 13 | 11.64 | 271(M)+ | C18H25NO | N-isobutyl-dodeca-2,4,8,10-tetraenamide (Anacycline) | 2.94 | 8.63 | - | - | - | 0.62 | 0.69 | 64.27 |
| 14 | 12.12 | 221(M)+ | C14H23NO | N-isobutyl-2,6,8-decatrienamide | 0.63 | - | 2.06 | - | 2.01 | - | 3.36 | - |
| 15 | 12.61 | 223(M)+ | C14H25NO | (2E,4E)-N-(2-methylpropyl)deca-2,4-dienamide (Pellitorine) | 1.16 | 6.04 | 0.78 | - | 2.73 | 13.21 | 2.49 | - |
| 16 | 12.94 | 274(M + H)+ | C18H27NO | Tetradeca-2E-diny-8,10-diynoic acid IBA | 0.77 | - | 0.59 | 2.72 | 3.61 | 1.28 | - | - |
| 17 | 13.39 | 270(M + H)+ | C18H23NO | Tetradeca-2E,4E, nE-trienoic-8,10-diynoic acid IBA | - | 2.85 | 1.86 | - | - | 6.61 | - | - |
| 18 | 13.67 | 102(M)+ | C5H10O2 | Isovaleric acid | 1.28 | 4.13 | 4.14 | - | 0.74 | 0.75 | 1.30 | - |
| 19 | 13.80 | 243(M)+ | C16H21NO | N-isobutyl-2,4-undecadiene-8,10-diynamide | - | - | - | - | 2.41 | - | 1.95 | - |
| 20 | 14.10 | 313(M)+ | C20H27NO2 | Dodeca-2E,4E, nE-trienoic acid 4-hydroxyphenylethylamide | 3.54 | 1.15 | 1.58 | 2.08 | 2.01 | 1.27 | 3.78 | - |
| 21 | 14.57 | 251(M)+ | C16H29NO | 2, 8)-N-isobutyl-2,8-dodecadienamide | 0.87 | - | 1.19 | 1.19 | 0.96 | - | 1.97 | 0.75 |
| 22 | 15.15 | 341(M)+ | C22H31NO2 | Tetradeca-2E,4E,8Etrienoic acid 4-hydroxyphenylethylamide | 0.61 | - | 0.82 | - | 1.06 | - | 2.06 | - |