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. 2021 Jan 13;26(2):392. doi: 10.3390/molecules26020392
J nucleation rate
A a kinetic constant that includes the attachment frequency of monomer molecules
N 0 the concentration of potential nucleation sites
Δg the height of the activation barrier
k the Boltzmann constant
T the absolute temperature
g(r)bulk the free energy of forming a new phase at a constant temperature in the absence of an interface
g(r)interfacial the interfacial free energy between the new phase and the old phase at a constant temperature
Δg(r)activation the height of the activation barrier at a constant temperature, which is the sum of g(r)bulk and g(r)interfacial
r the radius of the nucleus
P the actual vapor pressure
P 0 the saturation vapor pressure
γ the specific interfacial free energy
v m the molecular volume
r K the Kelvin radius. For a spherical nucleus, r = 2rK
n number of molecules in a nucleus
n* number of molecules in a critically sized nucleus
θ the contact angle of a spherical cap–shaped nucleus that forms on the substrate in the metastable parent phase
W(n) nucleation work, which is a function of the size of the nucleus