| J | nucleation rate |
| A | a kinetic constant that includes the attachment frequency of monomer molecules |
| N 0 | the concentration of potential nucleation sites |
| Δg | the height of the activation barrier |
| k | the Boltzmann constant |
| T | the absolute temperature |
| g(r)bulk | the free energy of forming a new phase at a constant temperature in the absence of an interface |
| g(r)interfacial | the interfacial free energy between the new phase and the old phase at a constant temperature |
| Δg(r)activation | the height of the activation barrier at a constant temperature, which is the sum of g(r)bulk and g(r)interfacial |
| r | the radius of the nucleus |
| P | the actual vapor pressure |
| P 0 | the saturation vapor pressure |
| γ | the specific interfacial free energy |
| v m | the molecular volume |
| r K | the Kelvin radius. For a spherical nucleus, r = 2rK |
| n | number of molecules in a nucleus |
| n* | number of molecules in a critically sized nucleus |
| θ | the contact angle of a spherical cap–shaped nucleus that forms on the substrate in the metastable parent phase |
| W(n) | nucleation work, which is a function of the size of the nucleus |