Figure 4.
Substrate scope for the conversion of glycidol and its derivatives 11 into the corresponding carbonates 12. Reaction conditions: 1.0 equiv. 11 (1.00 g), 5 mol % 8, 23 °C, 48 h, p(CO2)=1.0 MPa, solvent‐free. Isolated yields are given. [a] 24 h. [b] 2 mol % 8, 90 °C, 4 h. [c] 10 mol % 8, 45 °C, n‐butanol as solvent.