Table 1.

Chemical bonding analysis

Chemical Bond	Bond order A‐B	Local spin on A and B	EDA A→B vs A–B
Electron‐sharing	Large	Small/Null	|ΔEorb(A. + .B)|<|ΔEorb(A: + B)|
Donor‐acceptor	Small	Small/Null	|ΔEorb(A. + .B)|>|ΔEorb(A: + B)|
Spin‐Polarized	Small	Medium/Large	|ΔEorb(A. + .B)|<|ΔEorb(A: + B)|