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. 2021 Jan 29;12:675. doi: 10.1038/s41467-020-20662-7

Fig. 2. Ferroelectric property of the poled BOPVDF.

Fig. 2

a Comparison of the bipolar D-E loops for the fresh and poled BOPVDF films at 300 MV/m. b Progressive bipolar D-E loops for the poled BOPVDF under different electric fields at room temperature. The poling field has a sinusoidal waveform at 10 Hz. The inset shows the frequency-scan real part of the relative permittivity (εr′) at 25 °C. The extracted linear D-E loops from the deformational polarization (Ddef) of the poled BOPVDF film are also shown, following the method in a previous report (see Supplementary Note 3)19. After subtracting the Ddef loop from the bipolar D-E loops for the poled BOPVDF film, nonlinear P-E loops are obtained for c the two-phase and d the three-phase models. The inset two-phase model in c contains the β lamellar crystals and the isotropic amorphous fraction (IAF). The inset three-phase model in d contains the β crystals, the IAF, and the oriented amorphous fraction (OAF) connecting the lamellar crystal and the IAF. e First two consecutive bipolar D-E loops for the highly poled BOPVDF film after thermal annealing at different temperatures for 30 min. f Determination of instantaneous Pr, permanent Pr0, and Ec from the bipolar D-E loops in e for the highly poled BOPVDF at different temperatures.