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. Author manuscript; available in PMC: 2021 Apr 1.
Published in final edited form as: Synlett. 2020 Apr;31(6):587–591. doi: 10.1055/s-0039-1690851

Scheme 2:

Scheme 2:

Conjugate 1,4-Enone Reduction Using Organocatalyst 3aa

a Reaction conditions: enone 1 (0.27 mmol), HSiCl3 (1.35 mmol), catalyst 3a (0.027 mmol) in acetonitrile at 0 °C for 20 h; the yields in parenthesis are isolated yields after silica gel purification.