Table 1. 1H and 13C NMR Chemical Shift of Luteolin and Luteolin Oligomer I (MeOD-d4, 500 MHz).
Luteolin |
Luteolin oligomer I (major product) |
|||
---|---|---|---|---|
Position | 1H δ (ppm), J (Hz) | 13C δ (ppm) | 1H δ (ppm), J (Hz) | 13C δ (ppm) |
2 | 164.63 | 164.61 | ||
3 | 6.51 (1H, s) | 102.53 | 6.51 (1H, s) | 102.50 |
4 | 182.49 | 182.23 | ||
5 | 161.84 | 161.94 | ||
6 | 6.18 (1H, d, 2.3) | 98.77 | 6.17 (1H, m) | 98.74 |
7 | 164.96 | 165.01 | ||
8 | 6.41 (1H, d, 2.3) | 93.66 | 6.41 (1H, d, 2.3) | 93.60 |
8A | 177.03 | |||
9 | 158.05 | 157.40 | ||
10 | 103.97 | 103.66 | ||
1′ | 122.36 | 122.40 | ||
2′ | 7.35 (1H, m) | 112.85 | 7.35 (1H, m) | 112.73 |
3′ | 145.69 | 145.85 | ||
4′ | 149.65 | 149.65 | ||
4′A | 154.38 | |||
5′ | 6.88 (1H, dd, 8.9, 2.0) | 115.45 | 6.87 (1H, dd, 8.9, 2.0) | 115.38 |
6′ | 7.36 (1H, m) | 118.99 | 7.36 (1H, m) | 118.81 |