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. 2021 Jan 21;6(4):2999–3016. doi: 10.1021/acsomega.0c05387

Table 3. Elemental Analysis and Carbon Yield from Hydrodeoxygenation of Bio-oil at Different Temperatures and in the Presence of Different Catalysts.

   
elemental content of light bio-oil (wt %)
elemental ratio
   
substrate upgrading condition (temperature, catalysts) C H N O S H/O (by mol) H/C (by mol) C/O (by mol) bio-oil yield (wt %) carbon yielda (%)
raw EFB nab 42.25 5.88 1.03 50.75 0.09 1.85 1.67 1.11 na 100
raw bio-oil from EFB liquefaction na 30.81 9.1 6.36 42.27 na 3.44 3.54 0.97 61.41 44.78
upgraded bio-oil 300 °C Ni/Al2O3 28.84 9.56 5.9 48.1 na 3.18 3.98 0.80 46 43.06
Co/Al2O3 27.37 9.62 5.52 55.74 na 2.76 4.22 0.65 44 41.76
NiMo/Al2O3 25.44 9.66 5.94 41.05 na 3.77 4.56 0.83 45 41.83
CoMo/Al2O3 26.2 9.43 6.3 49.77 na 3.03 4.32 0.70 41 42.22
350 °C Ni/Al2O3 23.96 10.42 4.77 44.1 na 3.78 5.22 0.72 41 37.49
Co/Al2O3 29.66 10.27 4.02 49.43 na 3.32 4.16 0.80 27 33.42
NiMo/Al2O3 37.69 10.77 4.96 38.91 na 4.43 3.43 1.29 40 50.83
CoMo/Al2O3 38.21 10.3 4.01 35.11 na 4.69 3.23 1.45 35 35.48
a

In this work, the carbon yield was calculated from only the light bio-oil portion and the heavy oil portion was excluded.

b

na = not applicable.