Table 3. Elemental Analysis and Carbon Yield from Hydrodeoxygenation of Bio-oil at Different Temperatures and in the Presence of Different Catalysts.
|
elemental
content of light bio-oil (wt %) |
elemental ratio |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
substrate | upgrading condition (temperature, catalysts) | C | H | N | O | S | H/O (by mol) | H/C (by mol) | C/O (by mol) | bio-oil yield (wt %) | carbon yielda (%) | |
raw EFB | nab | 42.25 | 5.88 | 1.03 | 50.75 | 0.09 | 1.85 | 1.67 | 1.11 | na | 100 | |
raw bio-oil from EFB liquefaction | na | 30.81 | 9.1 | 6.36 | 42.27 | na | 3.44 | 3.54 | 0.97 | 61.41 | 44.78 | |
upgraded bio-oil | 300 °C | Ni/Al2O3 | 28.84 | 9.56 | 5.9 | 48.1 | na | 3.18 | 3.98 | 0.80 | 46 | 43.06 |
Co/Al2O3 | 27.37 | 9.62 | 5.52 | 55.74 | na | 2.76 | 4.22 | 0.65 | 44 | 41.76 | ||
NiMo/Al2O3 | 25.44 | 9.66 | 5.94 | 41.05 | na | 3.77 | 4.56 | 0.83 | 45 | 41.83 | ||
CoMo/Al2O3 | 26.2 | 9.43 | 6.3 | 49.77 | na | 3.03 | 4.32 | 0.70 | 41 | 42.22 | ||
350 °C | Ni/Al2O3 | 23.96 | 10.42 | 4.77 | 44.1 | na | 3.78 | 5.22 | 0.72 | 41 | 37.49 | |
Co/Al2O3 | 29.66 | 10.27 | 4.02 | 49.43 | na | 3.32 | 4.16 | 0.80 | 27 | 33.42 | ||
NiMo/Al2O3 | 37.69 | 10.77 | 4.96 | 38.91 | na | 4.43 | 3.43 | 1.29 | 40 | 50.83 | ||
CoMo/Al2O3 | 38.21 | 10.3 | 4.01 | 35.11 | na | 4.69 | 3.23 | 1.45 | 35 | 35.48 |
In this work, the carbon yield was calculated from only the light bio-oil portion and the heavy oil portion was excluded.
na = not applicable.