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. 2021 Jan 21;6(4):2665–2674. doi: 10.1021/acsomega.0c04837

Table 2. Optical Band Gap Energy and Phase Identification Evidenced from XRD and Raman Spectra for the As-Grown and Annealed Samples Deposited at Different Temperatures Using IPAa.

glass samples bandgap, Eg (eV) ± 0.01 Cu foil samples bandgap, Eg (eV) ± 0.01 phase composition (XRD and Raman)
G4(IPA30) 3.48 C4(IPA30) 3.47 ZnO
G5(IPA50) 3.37 C5(IPA50) 3.43 ZnO
G6(IPA65) 3.40 C6(IPA65) 3.45 ZnO
G4 Ann. 250 °C 3.28 C4 Ann. 250 °C 1.65 & 3.21 CuxO/ZnO
G5 Ann. 250 °C 3.21 C5 Ann. 250 °C 1.65 & 2.98 CuxO/ZnO
G6 Ann. 250 °C 3.15 C6 Ann. 250 °C 2.00 & 3.00 CuxO/ZnO
a

Crystallite sizes of the samples grown on the SLG substrate are shown in Table 1.