Table 2. Temperature and Mass Loss of Each Degradation Stage of Unprocessed PHBV, Processed PHBV and its Formulations with PLAP, Residual Mass Fraction at 500 °C, and the PLAP Mass Fraction Determined by TGA Analysis.
1st
stage |
2nd
stage |
|||||||
---|---|---|---|---|---|---|---|---|
wPLAP | Tonset (°C) | Tmax. (°C) | mass loss (%) | Tonset (°C) | Tmax. (°C) | mass loss (%) | R500°C (%) | wPLAP,realc |
0.00a | 240 | 300 | 100 | 0 | ||||
0.00 | 220 | 295 | 100 | 0 | ||||
0.10 | 205 | 260 | 92 | 285 | 345 | 8 | 0 | 0.09 |
0.20 | 200 | 255 | 85 | 280 | 350 | 14 | 1 | 0.17 |
0.30 | 200 | 255 | 75 | 280 | 350 | 23 | 2 | 0.28 |
1.00b | 190 | 280 | 11 | 300 | 385 | 87 | 2 |
Unprocessed PHBV.
Unprocessed PLAP.
wPLAP,real = {[(mass loss2ndstage/87) × 100] + residue}/100.