Table 3.

GC/mass for most promising C. vulgaris fractions cultivated under Cu (0.316 mg/L) as relative percentage

No.	Compound Name	M.wt	(Fractions number)				Biological activity	References
			1	5	6	7
1	4 h-1-benzopyran-4-one, 2-(3,4-dimethoxyphenyl)-3,5- dihydroxy-7-methoxy-	344				5.87	Antioxidant, antimicrobial, cancer enzyme inhibitors in pharmaceutical, cosmetics, and food industries	[45]
2	3,7,11,15-Tetramethyl-2-hexadecen-1-ol	296	2.95	1.33		2.52	anticancer, anti-inflammatory and antimicrobial,antioxidant activities	[46]
3	1-Nonadecene	266	1.10	3.14	6.02		Antimicrobial, antioxidant activity	[47, 48]
4	hexadecanoic acid, methyl ester	270	21.28	11.77	3.87	5.30	Antioxidant, antimicrobial,, hemolytic, hemolytic, 5-alpha reductase inhibitor cancer enzyme inhibitors in pharmaceutical, cosmetics, and food industries	[45, 49]
5	9-octadecenoic acid (z)-, methyl ester	296	23.02	57.86	6.39	9.05	Antioxidant, antimicrobial, cancer enzyme inhibitors in pharmaceutical, cosmetics, and food industries	[45, 49, 50]
6	1,2-benzenedicarboxylic acid	390	3.16		27.4	46.89	Antioxidant,antifouling, antimicrobial, cancer enzyme inhibitors in pharmaceutical, cosmetics, and food industries	[45, 49]
7	pentacosane	352	9.97	3.48			Antioxidant and antimicrobial activity	[51]
8	dotriacontane	450	2.11	2.83		1.38	Antimicrobial, antifungal anti-inflammatory, cytotoxic activity	[47]
9	phthalic acid, butyl tetradecyl ester	418		7.41		3.91	Antimicrobial activity	[46]
10	4 h-1-benzopyran-4-one,2-(3,4dihydroxyphenyl)-6,8-di-á-d-glucopyranosyl-5,7-dihydroxy-	610			1.17	3.33	Antioxidant, antimicrobial, cancer enzyme inhibitors in pharmaceutical, cosmetics, and food industries	[45]
11	7,9-di-tert-butyl-1-oxaspiro [4.5]deca-6,9-diene-2,8-dione	276		1.60	1.36		Antimicrobial activity	[52]
12	1-hexadecanol, 2-methyl-	256		1.71			anticancer, anti-inflammatory and antimicrobial,antioxidant activities	[49]
13	6,9,12,15-docosatetraenoic acid,methyl ester	346			1.79	4.18	phytopharmaceutical importance	[53]
14	Neophytadiene	278	5.43	4.27	4.06		Antioxidant, antibacterial activity	[54]
15	Methyl 4,7,10,13-hexadecatetraenoate	262	3.61				Antioxidant, antibacterial activity	[54]
16	Phytol	296	12.08				Antioxidant, antibacterial activity	[54]
17	9,12,15-octadecatrienoic acid,methyl ester, (z,z,z)-	292	14.49				Antimicrobial, antioxidant, anticancer	[45]
18	heptanoic acid, docosyl ester	438	0.93				Antioxidant and antifungal activity	[55]
19	3,3,3-Trifluoro-1-piperidin-1-yl-2-trif luoromethyl-propan-1-one	263		1.49
20	1,4-benzenediol, 2-(1,1-dimethylethyl)-5-(2-propenyl)-	206		3.10			Anticancer, Antioxidant activity and pesticidies	[56]
21	1,3-Dioxolane, 2-heptyl-4-phenyl-	248			4.32		Anti-inflammatory, anticarcinogenic and ant aging	[57]
22	Cycloheptasiloxane,tetradecamethyl-	518			1.34		antibacterial, antifungal, antifouling, immunomodulatory and antitumor activities	[58]
23	Corymbolone	208			2.04		Antioxidant, antimicrobial activity	[59]
24	spiro[4.5]decan-7-one, 1,8-dimethyl-8,9-epoxy-4-isopropyl-	236			1.88		Anticancer activity	[60]
25	8-(2-Acetyloxiran-2-yl)-6,6-dimethyl octa-3,4-dien-2-one	236			3.28
26	03027205002 flavone 4′-oh,5-oh,7-di-o-glucoside	428			1.21		Antioxidant activity	[61]
27	1,1'-bicyclopropyl]-2-octanoic acid, 2'-hexyl-, methyl ester	236			1.88		Anticancer activity	[53]
28	2-acetyl-3-(2-cinnamido)eth yl-7-methoxyindole	362			2.03	1.31	Antioxidant and antibacterial activity	[62]
29	1,2-benzenedicarboxylic acid, bis(8-methylnonyl) ester	446			3.35		Antioxidant, antimicrobial, anticancer	[45]
30	13-docosenamide, (z)-	337			24.85		Antioxidant, antitumor activity	[63]
31	2,2-dideutero octadecanal	270				2.01	Antimicrobial activity	[47]
32	hexadecanoic acid, 3[(trimethylsilyl)oxy] propyl ester	386				3.65
33	Hexanoic acid, 2-ethyl-,oxybis(2,1-ethanediyloxy-2,1-ethane diyl) ester	446				2.11
34	9,10-secocholesta-5,7,10(19)-triene-1,3-diol	488				1.05	Antiviral activity	[46]
35	S-(1,3-diphenylbutyl) dimethylthiocarbamate	311				2.06	Antioxidant and anticancer activity	[64]
36	Astaxanthin	596				2.18	Antioxidant activity	[65]