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Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Substituents, their corresponding Hammett constants (σp), and the classifications used in the current study. Negative values correspond to electron donating substituents and positive values correspond to electron withdrawing substituents.
Substituent
σp
Classification
N(CH3)2
−0.83 a
Donating
OCH3
−0.27 a
F
0.06 a
Withdrawing
Cl
0.23 a
Br
0.23 a
COOH
0.45 a
CF3
0.54 a
SO3H
0.64 b
CN
0.66 a
NO2
0.78 a
a Values taken from Hansch et al. [55]. b Values taken from Imaizumi et al. [56].