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. 2021 Jan 20;26(3):524. doi: 10.3390/molecules26030524

Table 1.

Substituents, their corresponding Hammett constants (σp), and the classifications used in the current study. Negative values correspond to electron donating substituents and positive values correspond to electron withdrawing substituents.

Substituent σp Classification
N(CH3)2 −0.83 a Donating
OCH3 −0.27 a
F 0.06 a Withdrawing
Cl 0.23 a
Br 0.23 a
COOH 0.45 a
CF3 0.54 a
SO3H 0.64 b
CN 0.66 a
NO2 0.78 a

a Values taken from Hansch et al. [55]. b Values taken from Imaizumi et al. [56].