Table 1.

Experimental band frequencies and assignments of Raman spectra for compounds 5, 7a, 7c, 10, 11, and 13.

Experimental Spectra (cm−1)
5	7a	7c	10	11	13
-	1719	1704	-	1715	1710	C=O stretching
1664	1652	1650	1625	1627	1629	C=C stretching in allyl/vinyl chains
1465–1450	1465–1450	1458	1465–1450	1465–1450	1458	CH3, CH2, CH bending in side chain and cycloalkane ring
-	1350	1367	1370	-	1360	P=O stretching, CH3, CH2, CH bending in side chain
1324	1325	1326	1325	1322	1334
1284	1265	1275	-	-	-	P-O stretching in O=P-O-C moiety
-	-	-	1260	-	1261	P-C stretching in O=P-C=C moiety
1234	1235	1235	1237	1234	1234	P=O, CH3, CH2, CH bending in side chain and cycloalkane ring
-	1170	1187	1170	1173	1186 s	P-O stretching, CH3, CH2, CH bending and C-C stretching in cycloalkane ring, C-O stretching
1143	1141	1145	-	-	1141
1105	1097	1098	1100	1100	1101
1038	1036	1044	1039	1039	1040
921	921	922	-	-	-	P-O bending in O=P-O-C moiety
-	-	-	790	795	792	P-C bending in O=P-C=C moiety
-	755	766	-	752	752	O-C=O stretching, CH3, CH2, CH bending in cycloalkane ring
736	745	732	735	735	735	CH3, CH2, CH bending in cycloalkane ring
704	708	707	704	704	707	CH3, CH2 in side chain, P-O stretching
662	665	657	661	661	662	CH3, CH2, CH bending in cycloalkane ring, in side chains, stretching C-C in cycloalkane ring
614	618	614	619	618	620
615	595	-	593	595	619
560	558	-	561	560	560 w
535	535	530	531	530	533 s
460	459	470	560	460	462	stretching C-C in cycloalkane ring, C-H bending
414	410	402	414	410	413
388	389	-	386	-	-
232	234	240	233	-	236	OH bending

vw—very weak, w—weak, s—strong.