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. Author manuscript; available in PMC: 2021 Mar 22.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Oct 6;60(13):6864–6878. doi: 10.1002/anie.202007001

Table 5.

O–H and S–H insertion reaction scope

graphic file with name nihms-1652543-t0005.jpg
entry[a] X R1 Ar, R2 # examples yield (%) ref.
1[b] O CH3 Ar, R2 = fluorenyl 1 100 69
3[e] O Ph, Ar, 2-napthyl, alkyl Ar, R2 = Ph 5 31–92 64
4[e] S Ph, Ar, 2-pyridyl, alkyl Ar, R2 = Ph 5 33–99 64
[a]

diazo compounds derived from tosylhydrazones for entries 1 and 2.

[b]

cis-[Pt(PPh3)2(CH3CN)2][BF4]2 41 catalyst

[e]

Fe(TPFPP)Ad 38 as catalyst