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. Author manuscript; available in PMC: 2021 Mar 22.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Oct 6;60(13):6864–6878. doi: 10.1002/anie.202007001

Table 8.

P–H insertion scope

graphic file with name nihms-1652543-t0008.jpg
entry R1 R2 catalyst # examples yield (%) ref.
1 alkoxy Ph, fluorenyl [Cu], 32 5 52–77 77
2[a], [b] aryl, alkoxy H, alkyl [Cu], 34 21 50–82 43
[a]

includes Ar = napthyl

[b]

diazo compounds derived from tosylhydrazones