Table 2.
Second order kinetic rate constants, half-lives and slopes of ZDV reacting with ozone in triplicate and confidence intervals (95%) in the presence (y = yes) and absence (n = no) of t-BuOH as radical scavenger.
| Experiment | pH | t-BuOH | slope | k [104 M−1 s−1] | t½ [s] |
|---|---|---|---|---|---|
| ZDV | 7 | y | 1.04 ± 0.04 | 3.11 ± 0.13 | 21.5 ± 0.9 |
| 7 | n | 0.93 ± 0.22 | 2.79 ± 0.65 | 23.9 ± 5.6 | |
| 3 | y | 1.05 ± 0.02 | 3.16 ± 0.06 | 21.1 ± 0.4 | |
| 3 | n | 1.06 ± 0.01 | 3.18 ± 0.02 | 21.0 ± 0.1 |