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. 2021 Jan 15;143(3):1307–1312. doi: 10.1021/jacs.0c12151

Table 1. Summary of Key Photophysical Properties of [Co(PhB(MeIm)3)2]+ in MeCNa.

  λ [nm] E [eV] ε [M–1 cm–1] f τ [μs] Φ [%]
abs 250 4.96 18000 1.7 × 10–1    
  310 4.00 400 6.5 × 10–3    
ESA 515 2.41 600   0.80  
em 690 1.80 17 1 × 10–10 0.82 >0.01
a

λ = wavelength of band, E = energy of band, ε = molar absorption coefficient, f = oscillator strength, τ = lifetime, Φ = quantum yield, abs = absorption, ESA = excited-state absorption, and em = emission.