Table. 4.

Synthetic applications^a.

^aReaction conditions: 1a (0.15 mmol), 2ac–2ag (0.1 mmol) or 1aa–1ac (0.1 mmol), 2a (0.15 mmol), Pd(PPh₃)₄ (5 mol %), K₂CO₃ (0.2 mmol), and DMA [0.1 M] under 40 W blue LED irradiation with fan cooling (30 ± 5 °C). All yields are isolated yields.

^bd.r. = 3:4.

^cd.r. = 2:1.

^dPd(PPh₃)₄ (10 mol %), 48 h.

^eE:Z = 1.3:1.

^fReaction conditions: 1a (0.2 mmol), 2ah–2al (0.1 mmol), Pd(PPh₃)₄ (5 mol %), K₂CO₃ (0.4 mmol), in DMA [0.1 M] under 40 W blue LED irradiation with fan cooling (30 ± 5 °C). All yields are isolated yields.