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. 2021 Feb 12;11:3704. doi: 10.1038/s41598-021-82179-3

Table 7.

Values of trueness [%] obtained using TXRF for the reference material IAEA-A-13 together with the lowest and highest values of the parameter met in examined literature.

Element Recommended value [μg/g] 95% Confidence Interval [μg/g] Measured value [μg/g] TXRF F-AAS GF-AAS ICP-OES ICP-MS
P 940# 690–1120 653 69 n.f. 99.7139*a 9013–99.884* 104119
S 6500 6000–7000 6219 95 96.1–109.4a141 n.f. 99 ± 14a148, 91 ± 2a148 100119
K 2500 2100–2700 2877 115 94–101a144 88 ± 7–104 ± 8a145 7213–10484* 98119–98.738*
Ca 286 226–332 469 164 102.434 n.f. 9471*–10569 6496*–10539*
Fe 2400 2200–2500 3048 127 97.834 9745*–106105* 91.5 ± 1.882–11347 71101*–111101*
Cu 4.3 3.7–4.8 5.6 130 104.134 96.460*–103.8110* 9047–10886* 81100*–125101*
Zn 13 12–14 18 140 95.1110*–95.9110* 9745* 8779–11371* 111 ± 3095
Se 0.24 0.15–0.31 0.22 92

97.8 ± 5.2a,b146,

102.2 ± 5.3a,b147

89.4–98.8a147 9183–1093* 62100*–125101*

#Information value;

*Calculated based on the literature data;

aValue from the paper that does not concern the analysis biomedical samples;

bDetermined using HG-AAS;

n.f. Value not found in discussed papers or not expressed in consistent unit.