Table 7.
Values of trueness [%] obtained using TXRF for the reference material IAEA-A-13 together with the lowest and highest values of the parameter met in examined literature.
Element | Recommended value [μg/g] | 95% Confidence Interval [μg/g] | Measured value [μg/g] | TXRF | F-AAS | GF-AAS | ICP-OES | ICP-MS |
---|---|---|---|---|---|---|---|---|
P | 940# | 690–1120 | 653 | 69 | n.f. | 99.7139*a | 9013–99.884* | 104119 |
S | 6500 | 6000–7000 | 6219 | 95 | 96.1–109.4a141 | n.f. | 99 ± 14a148, 91 ± 2a148 | 100119 |
K | 2500 | 2100–2700 | 2877 | 115 | 94–101a144 | 88 ± 7–104 ± 8a145 | 7213–10484* | 98119–98.738* |
Ca | 286 | 226–332 | 469 | 164 | 102.434 | n.f. | 9471*–10569 | 6496*–10539* |
Fe | 2400 | 2200–2500 | 3048 | 127 | 97.834 | 9745*–106105* | 91.5 ± 1.882–11347 | 71101*–111101* |
Cu | 4.3 | 3.7–4.8 | 5.6 | 130 | 104.134 | 96.460*–103.8110* | 9047–10886* | 81100*–125101* |
Zn | 13 | 12–14 | 18 | 140 | 95.1110*–95.9110* | 9745* | 8779–11371* | 111 ± 3095 |
Se | 0.24 | 0.15–0.31 | 0.22 | 92 |
97.8 ± 5.2a,b146, 102.2 ± 5.3a,b147 |
89.4–98.8a147 | 9183–1093* | 62100*–125101* |
#Information value;
*Calculated based on the literature data;
aValue from the paper that does not concern the analysis biomedical samples;
bDetermined using HG-AAS;
n.f. Value not found in discussed papers or not expressed in consistent unit.