Table 1.
Kinetic models | Initial concentration (mg/L) | ||||
---|---|---|---|---|---|
5 | 10 | 15 | 20 | 25 | |
Pseudo-first-order | |||||
K1 (min−1) | 0.012 | 0.008 | 0.068 | 0.157 | 0.087 |
qe (mg/g) | 0.106 | 1.102 | 0.362 | 0.539 | 0.821 |
R2 | 0.921 | 0.789 | 0.846 | 0.915 | 0.949 |
Pseudo-second-order | |||||
K2 (g/mg/min) | 3.815 | 0.423 | 0.564 | 0.530 | 0.292 |
qe (mg/g) | 1.128 | 2.262 | 3.546 | 4.736 | 5.845 |
R2 | 0.999 | 0.998 | 0.999 | 0.99 | 0.999 |
Elovich | |||||
β (g/mg) | 66.66 | 7.462 | 6.172 | 5.465 | 3.105 |
α (g/mg/min) | 0.062 | 0.233 | 0.120 | 0.055 | 0.128 |
R2 | 0.958 | 0.917 | 0.859 | 0.870 | 0.919 |
Intraparticle diffusion | |||||
Kid (g/mg/min) | 0.008 | 0.073 | 0.083 | 0.094 | 0.168 |
R2 | 0.968 | 0.845 | 0.691 | 0.697 | 0.757 |
Boyd | |||||
R2 | 0.922 | 0.789 | 0.847 | 0.915 | 0.950 |