Table 1.
Contents (µg/g, fresh weight base) of the 42 elements in pakchoi from 6 locations in Hanoi.
Element | LOD | LOQ | Cultivation region | |||||
---|---|---|---|---|---|---|---|---|
Tien Phong | Thanh Da | Linh Nam | Thanh Xuan | Van Duc | Van Noi | |||
(n = 10) | (n = 10) | (n = 10) | (n = 10) | (n = 10) | (n = 10) | |||
11B | 0.031 ± 0.002 | 0.103 ± 0.006 | <MQL | 2.225 ± 0.001 | 2.296 ± 0.149 | 1.679 ± 0.254 | 1.103 ± 0.028 | 1.367 ± 0.129 |
23Na | 2.220 ± 0.054 | 7.399 ± 0.179 | 740.7 ± 3.2 | 194.33 ± 3.43 | 343 ± 27 | 1056 ± 7 | 352.6 ± 3.6 | 401 ± 8 |
24Mg | 9.090 ± 0.081 | 30.29 ± 0.269 | 528.8 ± 5.1 | 543.4 ± 5.9 | 536.5 ± 49.1 | 543.1 ± 42 | 629.6 ± 10.5 | 518.6 ± 6.7 |
27Al | 1.100 ± 0.007 | 3.666 ± 0.023 | 58.85 ± 5.6 | 242.1 ± 7.7 | 130.5 ± 9.6 | 102.8 ± 1.2 | 305.8 ± 20.2 | 72.63 ± 4.16 |
28Si | 28.07 ± 0.103 | 93.55 ± 0.342 | 45.77 ± 3.2 | 37.53 ± 1.83 | 212.4 ± 10.8 | 302.5 ± 33.1 | 126.7 ± 1.8 | 163.9 ± 9.9 |
39K | 12.01 ± 0.051 | 40.02 ± 0.169 | 11369 ± 44 | 10464 ± 15 | 8683 ± 85 | 11915 ± 20 | 12113 ± 133 | 9220 ± 36 |
43Ca | 4.003 ± 0.011 | 13.34 ± 0.036 | 5422 ± 41 | 6425 ± 62 | 6626 ± 61 | 7517 ± 56 | 8268 ± 52 | 5983 ± 24 |
45Sc | 0.667 ± 0.004 | 2.223 ± 0.013 | 0.135 ± 0.011 | 0.272 ± 0.026 | 0.215 ± 0.121 | 0.213 ± 0.076 | 0.241 ± 0.012 | 0.207 ± 0.011 |
47Ti | 0.429 ± 0.003 | 1.429 ± 0.009 | 1.383 ± 0.012 | 2.726 ± 0.121 | 1.246 ± 0.122 | 2.062 ± 0.169 | 1.608 ± 0.073 | 1.255 ± 0.191 |
51V | 0.056 ± 0.006 | 0.186 ± 0.019 | 0.028 ± 0.002 | 0.065 ± 0.06 | 0.042 ± 0.003 | 0.034 ± 0.003 | 0.054 ± 0.002 | 0.031 ± 0.002 |
52Cr | 0.072 ± 0.001 | 0.239 ± 0.003 | 0.123 ± 0.003 | 0.121 ± 0.007 | 0.111 ± 0.004 | 0.192 ± 0.001 | 0.157 ± 0.006 | 0.214 ± 0.006 |
55Mn | 0.114 ± 0.002 | 0.379 ± 0.006 | 20.34 ± 1.07 | 9.976 ± 0.311 | 10.98 ± 0.11 | 22.9 ± 0.13 | 20.44 ± 0.18 | 14.11 ± 0.37 |
56Fe | 2.030 ± 0.007 | 6.765 ± 0.023 | 20.39 ± 1.05 | 50.89 ± 0.18 | 31.59 ± 2.35 | 26.17 ± 2.21 | 21.12 ± 1.94 | 26.97 ± 0.43 |
59Co | 0.005 ± 0.001 | 0.016 ± 0.003 | 0.018 ± 0.001 | 0.027 ± 0.002 | 0.041 ± 0.044 | 0.023 ± 0.002 | 0.026 ± 0.002 | 0.017 ± 0.001 |
60Ni | 0.023 ± 0.003 | 0.076 ± 0.009 | 0.117 ± 0.001 | 0.065 ± 0.003 | 0.061 ± 0.005 | 0.279 ± 0.002 | 0.274 ± 0.092 | 0.364 ± 0.015 |
63Cu | 0.027 ± 0.002 | 0.089 ± 0.006 | 0.35 ± 0.02 | 0.219 ± 0.011 | 0.441 ± 0.003 | 0.979 ± 0.019 | 0.702 ± 0.074 | 0.786 ± 0.036 |
66Zn | 0.703 ± 0.026 | 2.343 ± 0.086 | 7.148 ± 0.09 | 9.204 ± 0.811 | 8.674 ± 0.572 | 15.73 ± 1.21 | 16.74 ± 0.302 | 12.73 ± 0.156 |
69Ga | 0.070 ± 0.001 | 0.233 ± 0.003 | 0.399 ± 0.017 | 0.561 ± 0.005 | 0.636 ± 0.003 | 1.079 ± 0.025 | 1.835 ± 0.037 | 0.525 ± 0.035 |
75As | 0.005 ± 0.001 | 0.016 ± 0.003 | <MQL | 0.022 ± 0.002 | 0.041 ± 0.002 | 0.073 ± 0.19 | 0.044 ± 0.004 | 0.032 ± 0.003 |
85Rb | 0.004 ± 0.001 | 0.013 ± 0.003 | 3.111 ± 0.044 | 2.474 ± 0.218 | 4.783 ± 0.321 | 8.548 ± 0.581 | 6.638 ± 0.058 | 4.587 ± 0.139 |
88Sr | 0.091 ± 0.016 | 0.303 ± 0.053 | 17.77 ± 0.32 | 15.57 ± 0.57 | 13.6 ± 1.2 | 18.5 ± 0.8 | 17.18 ± 0.01 | 15.81 ± 0.02 |
89Y | 0.018 ± 0.001 | 0.059 ± 0.006 | 0.028 ± 0.004 | 0.046 ± 0.004 | 0.032 ± 0.001 | 0.044 ± 0.003 | 0.047 ± 0.002 | 0.0302 ± 0.0022 |
90Zr | 0.0021 ± 0.0001 | 0.006 ± 0.0003 | 0.006 ± 0.001 | 0.004 ± 0.001 | 0.017 ± 0.001 | 0.0048 ± 0.0003 | 0.021 ± 0.001 | 0.0062 ± 0.0004 |
93Nb | 0.0014 ± 0.0001 | 0.004 ± 0.0003 | 0.004 ± 0.001 | 0.004 ± 0.002 | 0.003 ± 0.003 | 0.0058 ± 0.004 | 0.016 ± 0.001 | 0.045 ± 0.002 |
95Mo | 0.032 ± 0.002 | 0.106 ± 0.006 | 0.075 ± 0.003 | 0.032 ± 0.003 | 0.026 ± 0.002 | 0.155 ± 0.002 | 0.070 ± 0.031 | 0.093 ± 0.003 |
105Pd | 0.0091 ± 0.0002 | 0.030 ± 0.0006 | 0.034 ± 0.002 | 0.056 ± 0.002 | 0.038 ± 0.003 | 0.039 ± 0.007 | 0.045 ± 0.003 | 0.035 ± 0.002 |
107Ag | 0.0041 ± 0.0001 | 0.013 ± 0.0003 | 0.106 ± 0.007 | 0.005 ± 0.001 | 0.005 ± 0.001 | 0.042 ± 0.003 | 2.687 ± 0.449 | 0.018 ± 0.001 |
111Cd | 0.0032 ± 0.0001 | 0.010 ± 0.0003 | 0.011 ± 0.001 | 0.023 ± 0.002 | 0.036 ± 0.003 | 0.027 ± 0.002 | 0.040 ± 0.003 | 0.033 ± 0.003 |
118Sn | 0.061 ± 0.002 | 0.203 ± 0.006 | 0.093 ± 0.004 | 0.015 ± 0.001 | 0.255 ± 0.013 | 0.121 ± 0.001 | 0.155 ± 0.009 | 0.123 ± 0.007 |
121Sb | 0.0035 ± 0.0001 | 0.011 ± 0.0003 | 0.042 ± 0.003 | 0.059 ± 0.004 | 0.041 ± 0.031 | 0.122 ± 0.005 | 0.131 ± 0.027 | 0.075 ± 0.005 |
133Cs | 0.0027 ± 0.0002 | 0.008 ± 0.0006 | 0.012 ± 0.001 | 0.039 ± 0.003 | 0.041 ± 0.002 | 0.035 ± 0.003 | 0.044 ± 0.001 | 0.020 ± 0.001 |
137Ba | 0.523 ± 0.048 | 1.743 ± 0.159 | 1.318 ± 0.094 | 1.31 ± 0.09 | 2.616 ± 0.111 | 2.763 ± 0.547 | 5.953 ± 0.479 | 1.64 ± 0.11 |
139La | 0.009 ± 0.001 | 0.029 ± 0.003 | 0.016 ± 0.002 | 0.042 ± 0.002 | 0.044 ± 0.002 | 0.036 ± 0.002 | 0.023 ± 0.002 | 0.020 ± 0.002 |
140Ce | 0.0052 ± 0.0001 | 0.017 ± 0.0003 | 0.018 ± 0.001 | 0.055 ± 0.002 | 0.031 ± 0.002 | 0.045 ± 0.002 | 0.057 ± 0.003 | 0.028 ± 0.007 |
141Pr | 0.0017 ± 0.0001 | 0.005 ± 0.0003 | 0.003 ± 0.000 | 0.011 ± 0.001 | 0.0043 ± 0.0003 | 0.006 ± 0.001 | 0.0057 ± 0.002 | 0.0028 ± 0.0001 |
146Nd | 0.010 ± 0.001 | 0.033 ± 0.003 | 0.012 ± 0.001 | 0.033 ± 0.002 | 0.015 ± 0.001 | 0.032 ± 0.013 | 0.024 ± 0.002 | 0.014 ± 0.001 |
147Sm | 0.0025 ± 0.0001 | 0.008 ± 0.0003 | <MQL | 0.008 ± 0.001 | 0.008 ± 0.001 | 0.014 ± 0.001 | 0.0032 ± 0.0002 | 0.0053 ± 0.0003 |
153Eu | 0.0028 ± 0.0002 | 0.009 ± 0.0006 | 0.003 ± 0.001 | 0.004 ± 0.001 | 0.006 ± 0.001 | 0.007 ± 0.498 | 0.014 ± 0.001 | 0.0038 ± 0.0001 |
157Gd | 0.0014 ± 0.0002 | 0.004 ± 0.0006 | 0.003 ± 0.001 | 0.011 ± 0.001 | 0.006 ± 0.001 | 0.013 ± 0.001 | 0.015 ± 0.001 | 0.0038 ± 0.0002 |
182W | 0.0011 ± 0.0001 | 0.003 ± 0.006 | 0.003 ± 0.001 | 0.002 ± 0.001 | 0.023 ± 0.002 | 0.014 ± 0.001 | 0.368 ± 0.007 | 0.012 ± 0.001 |
202Hg | 0.0005 ± 0.0000 | 0.001 ± 0.0001 | 0.003 ± 0.001 | 0.0011 ± 0.0001 | 0.005 ± 0.001 | 0.0058 ± 0.0003 | 0.0045 ± 0.003 | 0.0072 ± 0.0001 |
208Pb | 0.014 ± 0.001 | 0.046 ± 0.003 | 0.023 ± 0.002 | 0.0010 ± 0.0001 | 0.301 ± 0.002 | 0.489 ± 0.009 | 0.354 ± 0.002 | 0.512 ± 0.034 |
MQL, method quantification limit.