Table 3.
Rock–Eval data.
Shale | S1 | S2 | S3 | PC | RC | TOC | Tmax | HI | OI |
---|---|---|---|---|---|---|---|---|---|
Barnett | |||||||||
BGS | 0.26 | 8.18 | 0.19 | 0.72 | 0.91 | 1.63 | 421 | 502 | 12 |
WL | 0.24 | 8.22 | 0.24 | 0.70 | 0.96 | 1.66 | 421 | 495 | 14 |
Utica | |||||||||
BGS | 0.18 | 0.52 | 0.13 | 0.06 | 0.22 | 0.28 | 450 | 186 | 48 |
WL | 0.16 | 0.43 | 0.18 | 0.05 | 0.22 | 0.27 | 445 | 159 | 67 |
Marcellus | |||||||||
BGS | 0.09 | 0.30 | 0.30 | 0.05 | 6.83 | 6.88 | 640 | 4.3 | 4.7 |
WL | 0.24 | 0.37 | 0.29 | 0.05 | 6.48 | 6.53 | 609 | 5.7 | 4.4 |
S1—volatile hydrocarbon (HC) content, mg HC/g rock.
S2—thermally generated (cracked) hydrocarbon, mg HC/g rock.
S3—CO2 content, mg CO2/g rock.
PC—content of hydrocarbons volatilized and pyrolyzed, wt%.
RC—CO2 generated during oxidation representing remaining carbon, wt%.
TOC = PC + RC, wt%.
HI—hydrogen index = S2 × 100/TOC, mg HC/g TOC.
OI—oxygen index = S3 × 100/TOC, mg CO2/g TOC.
Tmax—temperature at which maximum of peak S2 occurs.