Table 4.
Rietveld refined parameters.
| sample | stoichiometry | unit cell (Å) | atomic displacement (Å2) |
||||
|---|---|---|---|---|---|---|---|
| K | P | R | C | N | |||
| A | K0Cu[Fe(CN)6]0.59 | 10.1030(1) | — | 3.0 | 0.31 | 7.3 | 0.79 |
| B | K0.23Cu[Fe(CN)6]0.49 | 9.9877(4) | 0.5a | 4.3 | a | 8.8 | 2.3 |
| C | K0.24Cu[Fe(CN)6]0.69 | 10.1007(2) | 0.5a | 0.83 | 0.33 | 4.9 | 2.2 |
| D | K1.10Cu[Fe(CN)6]0.73 | 10.0215(3) | 3.1 | 1.9 | 3.9 | 8.3 | 2.1 |
| E | KFeFe(CN)6 | 10.1691(7) | a | a | a | a | a |
| F | K0.25Fe[Fe(CN)6]0.79 | 10.1820(6) | a | a | a | a | a |
| G | K0.18Cu[Fe(CN)6]0.69 | 10.1279(2) | 0.5a | 1.2 | 0.24 | 4.7 | 0.67 |
| H | K0.74FeIII[FeIII/II(CN)6]0.67 | 10.2227(3) | a | a | a | a | a |
| I | K0.10Cu[Fe(CN)6]0.68 | 10.1038(2) | 0.5a | 1.1 | 0.15 | 3.3 | 4.0 |
| J | K1.51Cu[Fe(CN)6]0.79 | 10.0188(6) | 2.5 | 2.9 | 2.5 | 4.5 | 6.9 |
| K | K0.86Cu[Fe(CN)6]0.72 | 10.0264(2) | 5.6 | 1.3 | 1.7 | 6.3 | 0.85 |
| L | K1.86Mn[Fe(CN)6]0.97 | a: 6.9563(7) | 4.0 | 1.5 | 1.6 | C1: 0.73 | N1: 1.3 |
| b: 7.3279(7) | C2: 2.3 | N2: 0.21 | |||||
| c: 12.248(1) | C3: 0.57 | N3: 2.0 | |||||
aFixed.