Table 1.
Half‐wave potentials E 1/2 of CuII complexes vs. FcH/FcH+ in a 0.1 m KCl solution (water/acetonitrile=9:1) at room temperature.
Complex |
E 1/2 [V] |
Complex |
E 1/2 [V] |
---|---|---|---|
[Cu(phen)2]2+ |
−0.32 |
[Cu(CF3phen)2]2+ |
−0.21 |
[Cu(Fphen)2]2+ |
−0.23 |
[Cu(SCF3phen)2]2+ |
−0.16 |
[Cu(F2phen)2]2+ |
−0.11 |
[Cu(SF5phen)2]2+ |
−0.14 |