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. Author manuscript; available in PMC: 2021 Feb 22.
Published in final edited form as: J Am Chem Soc. 2020 Jun 24;142(27):11804–11817. doi: 10.1021/jacs.0c03085

Figure 2.

Figure 2.

Electronic absorption spectra for the generation of [FeIVpoat(O)]− (solid) from the treatment of [FeIIpoat]− (dashed) with IBX-iPr at −60 °C in a DMF:THF mixture. Inset: magnification of the low-energy region. The inset shows die orbitals involved in the electronic transitions.