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. Author manuscript; available in PMC: 2021 Feb 22.
Published in final edited form as: J Am Chem Soc. 2020 Jun 24;142(27):11804–11817. doi: 10.1021/jacs.0c03085

Figure 6.

Figure 6.

Parallel-mode EPR spectra (red) and simulations (black) of [FeIVpoat(O)] (A) and the [FeIVpoat(O)---LAII]+ adducts (B-E), all 10 mM in DMF:THF. The simulation parameters for S = 2 species are listed in Table 1. The signal at g=4.3 is an FeIII minority species. Instrumental parameters: 12 K, 9.32 GHz, 2mW.