Table 2.
Investigation of oxidative cleavage of trans-stilbene under optimum conditions in the presence of acidic additives.
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Entry | Catalyst | H2O2/Substrate (mmol/mmol) | T (°C) | Con. (%)a | Yield (%)b |
1 | A-CQDs/W (1 mol%) | 3/1 | 90 | 63 | 58 |
2 | A-CQDs/W (1 mol%) | 3/1 | 70 | 50 | 45 |
3 | A-CQDs/W (1 mol%) | 2/1 | 90 | 49 | 43 |
4 | A-CQDs/W (0.5 mol%) | 3/1 | 90 | 52 | 43 |
Reaction conditions: trans-Stilbene (1 mmol), H2O (1.5 mL), A-CQDs/W (1 mol %), 3 h.
aConversions were calculated based on initial mmol of trans-stilbene.
bIsolated Yields.