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. 2021 Feb 8;6(7):4511–4526. doi: 10.1021/acsomega.0c06070

Table 3. Selected Studies Demonstrating the Increasing Research on Nanocellulosic Materials/Systems as Adsorbents for the Removal of Various Pollutants.

title highlights year/refs
lead adsorption with sulfonated wheat pulp NCs inexpensive nanocellulosic materials were developed as effective adsorbents for the removal of Pb(II) in aqueous systems (119)
  Pb(II) was adsorbed efficiently at 1.2 mmol/g  
  sulfonated NC possessed a large area of binding sites for adsorbing the pollutant  
super light 3D hierarchical NC aerogel foam with superior oil adsorption NC and sodium dodecylsulfate (SDS) were used to produce 3D NC aerogel foam (NAF/SDS) via a high speed mechanical foaming and solvent-free method (120)
  the optimal concentration of NC and SDS for this 3D NAF/SDS was 0.4 and 0.4 wt %, respectively  
  the adsorption capacity of the foam was 206.79, 194.75, and 145.20 g g–1 for cyclohexane, ethyl acetate, and vacuum pump oil, respectively. These values were higher compared to conventional NC aerogel with adsorption capacities of 52.07, 81.12, and 34.52 g g–1 for the same chemicals  
magnetic NC-magnetite aerogel for easy oil adsorption the optimal fabricating conditions for these magnetic NC aerogel NCA/OA/Fe3O4 were 0.4 wt % NC, 3 mg L–1 oleic acid (OA), and 0.5 wt % Fe3O4 (121)
  the density of the aerogel fabricated was ∼9.2 mg cm–3, and the aerogel demonstrated a high adsorption capacity of 68.06 g g–1 for cyclohexane. This is lower than that reported by Zhang et al.120  
  ease of recyclability and good magnetic responsivity were key advantages of these materials  
hydrophobic NC aerogels as floating, sustainable, reusable, and recyclable oil absorbents highly porous nanocellulosic aerogels were prepared via vacuum freeze-drying from microfibrillated NC hydrogels (122)
  these aerogels were functionalized with hydrophobic oleophilic coating for selective oil adsorption and were capable of floating on water  
  the low density and potential to adsorb nonpolar liquids and oils up to nearly their own initial volume was demonstrated  
  modification of the aerogel’s surfaces further demonstrated the capability to collect organic pollutants from the water surface  
  ease of reusability and discarding (with adsorbed oil) makes these aerogels a versatile system for environmental remediation processes  
synthesis and characterization of multi carboxyl-functionalized NC/nanobentonite composite for the adsorption of uranium(VI) from aqueous solutions: kinetic and equilibrium profiles multicarboxylated functionalized polymer composite poly(itaconic acid)-poly(meth acrylic acid)-grafted-NC/nanobentonite (P(IA/MAA)-g-NC/NB) was synthesized and characterized (123)
  adsorption of U(VI) was pH-dependent, and an optimal pH of 5.5 promoted the removal in 120 min  
  no significant loss in performance was observed in the material even after six reuse/recycles  
biohybrid hydrogel and aerogel from self-assembled NC and nanochitin as a high-efficiency adsorbent for water purification a facial and novel self-assembled NC and nanochitin were developed as a highly efficient and versatile biohybrid hydrogel and aerogel for water purification (124)
  the self-assembly resulted from the electrostatic force between the one-dimensional charged TEMPO-oxidized cellulose nanofiber (TOCNF) and positively charged partly deacetylated chitin nanofiber (PDChNF) at room temperature with no addition of cross-linking agents  
  the resultant 3D system that physically cross-linked due to electrostatic interactions and hydrogen bonding exhibited adsorption capacities of 217 mg g–1 for arsenic(III) under neutral pH conditions and 531 mg g–1 for methylene blue under alkaline aqueous conditions, with rapid adsorption kinetics  
  these materials demonstrated good reusability; even after five successive reuse (adsorption–desorption cycles), the materials demonstrated an adsorption capacity of 505 mg g–1 for methylene blue