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. 2021 Feb 25;11:4515. doi: 10.1038/s41598-021-83854-1

Table 2.

Reduction of aromatic nitroarenes catalyzed by Fe3O4@Fritillaria/Pd NPsa.

Entry RC6H4NO2 Time (h) Yield (%)b TOF (10−3) (s−1)c
1 H 0.5 98 544
2 4-OH 0.5 98 544
3 2-OH 1 92 256
4 4-NH2 1 95 264
5 4-CH3 0.5 96 533
6 4-OCH3 0.5 95 528
7 4-CN 1 92 256
8 2-NH2 2 88 122
9 4-CHO 1.5 85 157
10 4-Cl 1.5 80 148

aReaction conditions: Nitroarene (1.0 mmol), NH2NH2. H2O (3.0 mmol), catalyst (0.1 mol%), EtOH:H2O (1:2, 3.0 mL), 80 °C; bIsolated yields; cturnover frequencies (TOF = (Yield/Time)/Amount of catalyst (mol).