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Schematic representation of the electrochemiluminescence imaging. The luminophore Ru(bpy)32+ and coreactant TPrA are oxidized at the heterogeneous interface between the microbowls and the ITO supporting electrode with the aid of enhanced electric field, generating the excited state Ru(bpy)32+∗. The accelerated ECL emission is produced during the relaxation of Ru(bpy)32+∗ back to the ground state.
