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General, simplified synthetic routes for the preparation of thioureate 2, carbamate I (3) and carbamate II (4). Synthesis of the binding motif of thioureate 2 was conducted by a solid phase procedure, whereas binding motifs 15 (carbamate I) and 17 (carbamate II) were obtained by solution phase synthesis prior to coupling to compound 18. Detailed synthesis procedures are given in the supporting information
