Table 2.

Crystallographic data for [Ag(NO₃)(NC₁₀H₁₄NC₆H₄)] (6a) and SO₂NC₁₀H₁₄NC₆H₄CH₃ (11).

	[Ag(NO3)(NC10H14NC6H4)]	SO2NC10H14NC6H4CH3-4
Empirical formula	Ag2N6C32H36O6	N4C34H40O4S2
Formula weight	816.42	632.82
Crystal system	Monclinic	Orthorhombic
Space group	C2	P212121
Unit cell dimensions
a/Å	28.720 (5)	8.9160 (3)
b/Å	7.3319 (9)	12.0253 (4)
c/Å	7.2379 (9)	14.8492 (4)
α/deg	90	90
β/deg	95.29 (1)	90
γ/deg	90	90
Volume (Å−3)	1517.6 (4)	1592.10 (9)
Z, Dcal (g/cm3)	2, 1.787	2, 1.320
Absorption coefficient (mm−1)	1.347	0.212
F(000)	824	672
Crystal size (mm3)	0.3 × 0.2 × 0.3	0.2 × 0.3 × 0.2
θ range for data collection (deg)	1.4 to 33.0	2.2 to 32.6
Index ranges	−37 ≤ h ≤ 43, −8 ≤ k ≤ 11, −11 ≤ l ≤ 11	−13 ≤ h ≤ 13, −16 ≤ k ≤ 18, −22 ≤ l ≤ 22
Reflections collected / unique	7272/4840 [R(int) = 0.048]	22635/5803 [R(int) = 0.050]
Data/restraints/parameters	4840/1/211	5803/0/202
Final R (observed)	R1 = 0.065, wR2 = 0.19	R1 = 0.034, wR2 = 0.092