Table 2.
λmax (nm), pKa, Eox (V) and bond dissociation energy (BDE) values (kcal/mol) for selected compounds [17,27,39,46,56,61].
Compound | λradical | λanion | λhydrazine | pKa | Eox | BDE |
---|---|---|---|---|---|---|
DPPH | 518 | 424 | 322 | 8.54 | 0.30 | 75.3 |
1 | 512 | 383 | 337 | 11.3 | 0.13 | 74.5 |
9 | 500 | 505 | 352 | 7.35 | 0.49 | - |
10 | 500 | 485 | 352 | 6.49 | 0.60 | - |
12 | 524 | 413 | 353 | 8.20 | 0.34 | 82 |
13 | 506 | 441 | 363 | 10.7 | 0.25 | 76.4 |
23 | 500 | 365 | 346 | 11.1 | 0.24 | 76.3 |
25 | 524 | 655 | 324 | 12.5 | 0.87 | 76.81 |
26 | 517 | 495 | 330 | 11.6 | 1.17 | 76.96 |
27 | 517 | 492 | 332 | 10.9 | 1.23 | 70.67 |
28 | 486 | 620 | 392 | 7.82 | 0.173 | 75.45 |
29 | 507 | 645 | 404 | 8.07 | 0.107 | 75.08 |
30 | 510 | 654 | 482 | 8.33 | 0.130 | 75.30 |