Table 1.
1H (500 MHz) and 13C NMR (125 MHz) spectral data of compound 1 in acetone-d6.
Position | 1H | 13C | HMBC (Correlation with 1H) |
---|---|---|---|
1 | - | 137.4 | 1-OMe |
2 | - | 136.9 | 4 |
3 | - | 141.7 | 4 * |
4 | 6.21 (s) | 109.7 | 7 |
5 | - | 117.9 | 7 *, 8 |
6 | - | 140.0 | 4, 7 |
7 | 4.12 (dd, J = 7.0, 5.5 Hz) | 39.7 | 4, 8 * |
8 | 2.67 (m), 2.74 (m) | 45.9 | 7 *, 10, 14 |
9 | - | 130.9 | 7, 8 *, 13 |
10 | 6.13 (d, J = 2.0 Hz) | 114.2 | 8, 14 |
11 | - | 147.5 | 13, 11-OMe |
12 | - | 145.8 | 10, 14 |
13 | 6.56 (d, J = 8.0 Hz) | 115.1 | - |
14 | 6.22 (dd, J = 8.0, 2.0 Hz) | 122.9 | 8, 10 |
1′ | - | 147.2 | 6′ *, 1′-OMe |
2′ | - | 134.0 | 6′ |
3′ | - | 142.4 | 7 |
4′ | - | 119.0 | 7 *, 8, 6′, 7′ |
5′ | - | 129.8 | 7, 8′ |
6′ | 6.66 (s) | 108.5 | 7′ |
7′ | 2.76 (m), 2.84 (m) | 34.5 | 6′, 8′ * |
8′ | 2.80 (m) | 38.0 | 7′ *, 10′, 14′ |
9′ | - | 134.2 | 8′ *, 13′ |
10′ | 6.77 (d, J = 2.0 Hz) | 112.9 | 8′, 14′ |
11′ | - | 148.1 | 13′, 11′-OMe |
12′ | - | 145.6 | 10′, 14′ |
13′ | 6.71 (d, J = 8.5 Hz) | 115.6 | - |
14′ | 6.69 (dd, J = 8.5, 2.0 Hz) | 121.6 | 8′, 10′ |
MeO-1 | 3.89 (s) | 61.1 | - |
MeO-1′ | 3.81 (s) | 56.7 | - |
MeO-11 | 3.56 (s) | 55.9 | - |
MeO-11′ | 3.76 (s) | 56.2 | - |
* Two-Bond coupling.