Table 2.
Pos. | 1 ** | 2 *** | 3 ** | 4 ** | 7 ** | Pos. | 1 ** | 2 *** | 3 ** | 4 ** | 7 ** |
---|---|---|---|---|---|---|---|---|---|---|---|
1 | 93.95 | 94.03 | 93.82 | 93.76 | 93.83 | 3″ | 69.45 | 69.22 | 69.46 | 69.39 | 68.84 |
3 | 141.14 | 141.75 | 141.14 | 141.12 | 140.97 | 4″ | 71.05 | 70.70 | 71.07 | 70.90 | 74.15 |
4 | 102.06 | 102.46 | 101.95 | 101.80 | 102.09 | 5″ | 66.89 | 65.89 | 66.88 | 66.65 | 66.86 |
5 | 35.78 | 35.80 | 35.81 | 35.75 | 35.93 | 6″ | 16.53 | 17.62 | 16.54 | 16.35 | 16.54 |
6 | 83.74 | 83.21 | 83.61 | 83.47 | 82.77 | 1‴ | 134.00 | 134.11 | 133.97 | 134.07 | 134.32 |
7 | 58.02 | 57.56 | 58.14 | 58.07 | 58.13 | 2‴–6‴ | 128.01–130.45 | 129.01–131.26 | 128.00–130.43 | 128.04–130.46 | 127.95–130.26 |
8 | 65.08 | 66.62 | 65.21 | 65.19 | 65.25 | 7‴ | 146.28 | 146.07 | 146.26 | 146.04 | 145.39 |
9 | 41.85 | 42.14 | 41.92 | 41.87 | 41.91 | 8‴ | 116.50 | 117.41 | 116.51 | 116.47 | 117.42 |
10 | 60.17 | 59.22 | 60.07 | 60.01 | 60.06 | 9‴ | 165.93 | 165.75 | 165.92 | 165.89 | 166.98 |
1′ | 98.45 | 98.71 | 98.36 | 98.32 | 98.32 | 1″″ | 134.00 | - | 133.97 | - | - |
2′ | 73.35 | 73.70 | 73.44 | 73.42 | 73.42 | 2″″–6″″ | 128.01–130.45 | - | 128.00–130.43 | - | - |
3′ | 76.02 | 76.51 | 76.28 | 76.27 | 76.25 | 7″″ | 146.07 | - | 146.05 | - | - |
4′ | 70.06 | 70.26 | 70.37 | 70.37 | 70.35 | 8″″ | 116.50 | - | 116.51 | - | - |
5′ | 74.36 | 74.22 | 77.22 | 77.22 | 77.19 | 9″″ | 166.31 | - | 166.30 | - | - |
6′ | 62.74 | 63.27 | 61.58 | 61.55 | 61.52 | Acetyl: 6′ | 19.54, 171.40 | 20.94, 170.72 | - | - | |
1″ | 96.41 | 96.11 | 96.41 | 96.28 | 99.06 | 2″ | 19.48, 170.32 | 21.07, 170.23 | 19.49, 170.31 | 19.37, 170.30 | - |
2″ | 69.92 | 69.55 | 70.11 | 69.92 | 71.05 | 4″ | - | 21.04, 170.06 | - | 19.39, 170.53 | - |
* Assignments based on DEPT135, COSY, HSQC, HMBC, H2BC, NOESY experiments and comparison with reported data. ** Spectra measured in CD3OD. *** Spectra measured in DMSO d6.