|
|
ion [i] concentration within pore, mol·m−3
|
|
|
feed-solution concentration, mol·m−3
|
|
|
ion [i] in feed-solution concentration, mol·m−3
|
|
|
uncharged solute bulk permeate concentration, mol·m−3
|
|
/
|
uncharged solute/charged solute pore diffusion coefficient,
|
|
|
solute bulk diffusion coefficient, m2.s−1
|
| e |
electronic charge,
|
| I |
ionic strength, mol·m−3
|
| j |
number of data points per solute in fitting, dimensionless |
|
|
ionic flux of ion [i] (pore area basis), mol·m−2·s−1
|
|
|
uncharged solute flux (pore area basis), mol·m−2·s−1
|
| k |
feed-side mass transfer coefficient, m/s |
| k |
Boltzmann constant,
|
|
|
hindrance factor for convection of ion I, dimensionless |
|
|
ionic hindrance factor for diffusion, dimensionless |
| P |
pressure N/m2
|
|
|
effective pore radius, m |
| R |
rejection (%) |
| R |
universal gas constant,
|
| V |
solvent velocity, m/s |
|
|
effective charge density, mol/m3
|
| T |
absolute temperature in K |
|
|
ion [i] valence, dimensionless |
| x |
axial position within the pore, m |
|
|
the activity coefficient of ion [i] within the pore, dimensionless |
|
|
applied pressure, N·m−2
|
|
|
the bulk activity coefficient of ion [i], dimensionless |
|
|
effective pressure driving force, N·m−2
|
|
|
membrane thickness, m |
|
|
the osmotic pressure difference, N·m−2
|
| λ |
the ratio of ionic or uncharged solute radius to pore radius, dimensionless |
|
|
Donnan potential, V |
| η |
solvent viscosity within pores, N·s·m−2
|
|
|
bulk/pore dielectric constant, dimensionless |
|
|
the ratio of effective membrane charge density to bulk feed concentration, dimensionless
|
|
|
the ratio of ionic radius to pore radius, dimensionless |
|
|
the steric partition coefficient of ion [i], dimensionless |
|
|
the potential within the pore, V |