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. 2021 Feb 14;11(2):130. doi: 10.3390/membranes11020130
ci ion [i] concentration within pore, mol·m−3
Cf feed-solution concentration, mol·m−3
Ci ion [i] in feed-solution concentration, mol·m−3
Cp uncharged solute bulk permeate concentration, mol·m−3
Dp/ Di,p uncharged solute/charged solute pore diffusion coefficient, m2.s1 (=KdD)
D solute bulk diffusion coefficient, m2.s−1
e electronic charge, 1.602177×1019C
I ionic strength, mol·m−3
j number of data points per solute in fitting, dimensionless
ji ionic flux of ion [i] (pore area basis), mol·m−2·s−1
js uncharged solute flux (pore area basis), mol·m−2·s−1
k feed-side mass transfer coefficient, m/s
k Boltzmann constant, 1.38066×1023JK1
Ki,c hindrance factor for convection of ion I, dimensionless
Ki,d ionic hindrance factor for diffusion, dimensionless
P pressure N/m2
rp effective pore radius, m
R rejection (%)
R universal gas constant, 8.314 J·mol1·K1
V solvent velocity, m/s
Xd effective charge density, mol/m3
T absolute temperature in K
zi ion [i] valence, dimensionless
x axial position within the pore, m
γi the activity coefficient of ion [i] within the pore, dimensionless
ΔP applied pressure, N·m−2
γi0 the bulk activity coefficient of ion [i], dimensionless
ΔPe effective pressure driving force, N·m−2
Δx membrane thickness, m
ΔΠ the osmotic pressure difference, N·m−2
λ the ratio of ionic or uncharged solute radius to pore radius, dimensionless
ΔΨD Donnan potential, V
η solvent viscosity within pores, N·s·m−2
εbεp bulk/pore dielectric constant, dimensionless
ξ the ratio of effective membrane charge density to bulk feed concentration, dimensionless (ξ=Xd/Cf)
λi the ratio of ionic radius to pore radius, dimensionless
Φi the steric partition coefficient of ion [i], dimensionless
Ψ the potential within the pore, V