Scheme 5.
Key carbon–carbon bond-forming reactions in the total synthesis of herboxidiene/GEX 1A.[32] Bn=benzyl, DTBP=2,6-di-tert-butyl-pyridine, TBDPS=tert-butyldiphenylsilyl, Tf=trifluoromethanesulfonyl, TMS=trimethylsilyl.
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